IOCAS-IR  > 海洋环境腐蚀与与生物污损重点实验室
pH -responsible self-healing performance of coating with dual-action core-shell electrospun fibers
Ji, Xiaohong1; Wang, Wei2,3,6; Li, Weihua1,2,4,5; Zhao, Xia2,5; Liu, Ang2,5; Wang, Xin2,5; Zhang, Xiaoying2,5; Fan, Weijie2,5; Wang, Yani1; Lu, Zhaoxia1; Liu, Shuan6; Shi, Hao7
2019-11-01
Source PublicationJOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS
ISSN1876-1070
Volume104Pages:227-239
Corresponding AuthorWang, Wei(wangwei8038@ouc.edu.cn) ; Li, Weihua(liweihua@qdio.ac.cn)
AbstractpH-responsible self-healing core-shell electrospun nanofibers encapsulating oleic acid (OA) and benzotriazole (BTA) corrosion inhibitors were synthesized and added into a coating material for the corrosion protection of carbon steels. The shell of electrospun nanofibers were poly(vinyl alcohol) (PVA), and the healing agents OA and BTA were used as core materials to reseal a damaged region. The average nanofiber diameters was 350 nm, and the surface is smooth, without any bead structure. OA plays a critical role on corrosion inhibitor in 3.5% alkaline sodium chloride solution and the maximum inhibition efficiency was 86.0% after 10 days immersion. BTA works in 3.5% acidic sodium chloride solution and the maximum inhibition efficiency was 83.4% after 5 days immersion. The anti-corrosion and self-healing capability of core-shell coating were evaluated through scanning electron microscopy, transmission electron microscopy, confocal laser fluorescence microscopy, Fourier transform infrared spectroscopy, electrochemical measurement technology, thermo gravimetric analysis, and material test system rack. Results showed that core-shell spinning fibers with corrosion inhibitors at different concentrations were prepared successfully. The core-shell fibers released the inhibitors to form an OA protective film and a BTA passivation film on the exposed metal surface. Electrochemical measurement monitored specifically the self-healing properties of the coating. These result potentially have important value for the design and research of self-healing materials in the future. (C) 2019 Taiwan Institute of Chemical Engineers. Published by Elsevier B.V. All rights reserved.
KeywordSelf-healing Core-shell fibers Oleic acid Electrochemical measurements Fluorescence property
DOI10.1016/j.jtice.2019.06.022
Indexed BySCI
Language英语
Funding ProjectNational Natural Science Foundation of China[51525903] ; Qingdao National Laboratory for Marine Science and Technology[2017ASTCP-OS09] ; Key Research and Development Projects in Shandong Province[2018GG102035] ; Natural Science Foundation of Guangxi Province[2018GXNSFBA138059] ; Key Research and Development Project of Shandong Province[2017GGX20101] ; Qingdao Science and Technology Plan[18-2-2-9-jch] ; Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences[2018K04] ; Foundation of Key Laboratory of Marine Materials and Related Technologies ; AoShan Talents Outstanding Scientist Program
WOS Research AreaEngineering
WOS SubjectEngineering, Chemical
WOS IDWOS:000496607300024
PublisherELSEVIER
Citation statistics
Cited Times:7[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.qdio.ac.cn/handle/337002/165086
Collection海洋环境腐蚀与与生物污损重点实验室
Corresponding AuthorWang, Wei; Li, Weihua
Affiliation1.Guangxi Univ, Sch Chem & Chem Engn, Nanning 530004, Peoples R China
2.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, Qingdao 266071, Shandong, Peoples R China
3.Ocean Univ China, Sch Mat Sci & Engn, 238 Songling Rd, Qingdao 266100, Shandong, Peoples R China
4.Sun Yat Sen Univ, Sch Chem Engn & Technol, Zhuhai 519082, Peoples R China
5.Qingdao Natl Lab Marine Sci & Technol, 1 Wenhai Rd, Qingdao 266237, Shandong, Peoples R China
6.Chinese Acad Sci, Zhejiang Key Lab Marine Mat & Protect Technol, Ningbo Inst Mat Technol & Engn, Key Lab Marine Mat & Related Technol, Ningbo 315201, Zhejiang, Peoples R China
7.Shandong Univ Sci & Technol, Coll Mech & Elect Engn, Qingdao 266590, Shandong, Peoples R China
Corresponding Author AffilicationKey Laboratory of Marine Environmental Corrosion and Bio-fouling, IOCAS
Recommended Citation
GB/T 7714
Ji, Xiaohong,Wang, Wei,Li, Weihua,et al. pH -responsible self-healing performance of coating with dual-action core-shell electrospun fibers[J]. JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS,2019,104:227-239.
APA Ji, Xiaohong.,Wang, Wei.,Li, Weihua.,Zhao, Xia.,Liu, Ang.,...&Shi, Hao.(2019).pH -responsible self-healing performance of coating with dual-action core-shell electrospun fibers.JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS,104,227-239.
MLA Ji, Xiaohong,et al."pH -responsible self-healing performance of coating with dual-action core-shell electrospun fibers".JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS 104(2019):227-239.
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