IOCAS-IR  > 海洋地质与环境重点实验室
A Direct Quantitative Raman Method for the Measurement of Dissolved Bisulfate in Acid-Sulfate Fluids
Xi, Shichuan1,2,3,4; Zhang, Xin1,2,3,4; Luan, Zhendong1,2; Du, Zengfeng1,2; Li, Lianfu1,2,4; Wang, Bing1,2,4; Cao, Lei1,2; Lian, Chao1,2; Yan, Jun1,2
2018-08-01
Source PublicationAPPLIED SPECTROSCOPY
ISSN0003-7028
Volume72Issue:8Pages:1234-1243
Corresponding AuthorZhang, Xin(xzhang@qdio.ac.cn)
AbstractRaman spectroscopy has been applied to the quantitative analysis of the concentration of bisulfate in acid-sulfate fluids at different temperatures. The quantitative analysis method is based on the peak area ratios of HSO4-(v(1)) and H2O(v(2)), where PA(HSO4-/H2O) = [HSO4-] x (0.0066 x T+ 1.3070) at a temperature range of 0-100 degrees C. We found that the molal scattering coefficient of bisulfate increases slightly at the elevated temperature may be due to the changes of fraction of water molecules that are hydrogen-bonded. The method can also be applied to analyze physicochemical parameters of other acid fluids, such as hydrogen phosphate, bicarbonate, etc., and especially to the in situ detection of deep sea acid-sulfate hydrothermal fluids in the future.
KeywordQuantitative analysis acid sulfate bisulfate concentration Raman spectroscopy
DOI10.1177/0003702818773117
Indexed BySCI
Language英语
Funding ProjectNational Natural Science Foundation of China[41576104] ; Key Research Program of Frontier Sciences, CAS[QYZDB-SSW-DQC004] ; Strategic Priority Research Program, CAS[XDA11040301] ; Strategic Priority Research Program, CAS[XDA11030301] ; Open Research Project of National Major Science & Technology Infrastructure (RV KEXUE)[NMSTI-KEXUE2017K01] ; NSFC-Shandong Joint Fund for Marine Science Research Centers[U1606401] ; National Key R&D Program of China[2016YFC0302103] ; Taishan Scholar Project Funding[tspd20161007]
WOS Research AreaInstruments & Instrumentation ; Spectroscopy
WOS SubjectInstruments & Instrumentation ; Spectroscopy
WOS IDWOS:000440337500009
PublisherSAGE PUBLICATIONS INC
Citation statistics
Document Type期刊论文
Identifierhttp://ir.qdio.ac.cn/handle/337002/160007
Collection海洋地质与环境重点实验室
Corresponding AuthorZhang, Xin
Affiliation1.Chinese Acad Sci, Inst Oceanol, CAS Key Lab Marine Geol & Environm, Qingdao, Peoples R China
2.Chinese Acad Sci, Inst Oceanol, Ctr Deep Sea Res, Qingdao, Peoples R China
3.Qingdao Natl Lab Marine Sci & Technol, Lab Marine Geol, Qingdao, Peoples R China
4.Univ Chinese Acad Sci, Beijing, Peoples R China
First Author AffilicationInstitute of Oceanology, Chinese Academy of Sciences;  Chinese Acad Sci, Inst Oceanol, Ctr Deep Sea Res
Corresponding Author AffilicationInstitute of Oceanology, Chinese Academy of Sciences;  Chinese Acad Sci, Inst Oceanol, Ctr Deep Sea Res
Recommended Citation
GB/T 7714
Xi, Shichuan,Zhang, Xin,Luan, Zhendong,et al. A Direct Quantitative Raman Method for the Measurement of Dissolved Bisulfate in Acid-Sulfate Fluids[J]. APPLIED SPECTROSCOPY,2018,72(8):1234-1243.
APA Xi, Shichuan.,Zhang, Xin.,Luan, Zhendong.,Du, Zengfeng.,Li, Lianfu.,...&Yan, Jun.(2018).A Direct Quantitative Raman Method for the Measurement of Dissolved Bisulfate in Acid-Sulfate Fluids.APPLIED SPECTROSCOPY,72(8),1234-1243.
MLA Xi, Shichuan,et al."A Direct Quantitative Raman Method for the Measurement of Dissolved Bisulfate in Acid-Sulfate Fluids".APPLIED SPECTROSCOPY 72.8(2018):1234-1243.
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