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太平洋富钴结壳稀有气体地球化学特征及其成矿指示意义
其他题名Noble Gas Geochemistry of Ferromanganese Crusts from Pacific Ocean and Their Significations for the Formation of Crusts
卜文瑞
学位类型博士
2008-06-12
学位授予单位中国科学院海洋研究所
学位授予地点海洋研究所
关键词富钴结壳 稀有气体 同位素地球化学 铂族元素 地幔不均一性
摘要中西太平洋富钴结壳稀有气体核素含量和同位素组成具有明显的区域性特征。依其He同位素比值与大洋中脊玄武岩(MORB)He同位素比值的相对大小,可将富钴结壳分为低3He/4He型和高3He/4He型两类,麦哲伦海山、马尔库斯-威克海岭、马绍尔群岛海山链和中太平洋海山产出低3He/4He型结壳,莱恩群岛海山链产出高3He/4He型结壳。 富钴结壳稀有气体以下地幔来源为主,低3He/4He型与高3He/4He型结壳稀有气体特征的差异是二者产出海山链下地幔源区类型不同的表现。低3He/4He型结壳中的稀有气体主要来自受俯冲再循环大洋地壳影响的HIMU型地幔源区,高3He/4He型结壳中的稀有气体主要来自受捕获大气组分沉积物再循环作用影响的EM型地幔源区。地幔源区类型的差异是引起两类结壳稀有气体组成差异的根本原因。 富钴结壳铂族元素(PGE)特征随海山链而变化,PGE各元素之间也有明显的分异,暗示了结壳PGE来源的多样性和富集机制的差异性。地外物质对富钴结壳PGE的贡献有限,富钴结壳PGE主要来自海底幔源岩石的蚀变作用和陆源物质输入。PGE来源印证了富钴结壳稀有气体的地幔来源说。 大洋岛屿玄武岩(OIB)低温蚀变作用研究和质量平衡理论计算表明,OIB低温蚀变作用为海水提供了大量金属,OIB是富钴结壳重要的矿源场。地幔在富钴结壳成矿中起着重要的作用。
其他摘要The nuclide contents and isotopic ratios of ferromanganese crusts from the western and central Pacific Ocean vary significantly with regional characteristics. Based on the relationship between the He isotope ratios of samples and that of MORB, the samples can be classified into two types: a low 3He/4He type and a high 3He/4He type. The sample from the Magellan Seamounts, Marcus-Wake Seamounts, Marshall Island Chain and the Mid-Pacific Seamounts are low 3He/4He type crusts, while the samples from the Line Island Chain are high 3He/4He type crusts. The noble gases in ferromanganese crusts originate predominantly from the lower mantle of the Earth. The differences in noble gas characteristics between the low 3He/4He type and the high 3He/4He type crusts indicate the differences of lower mantle end-member of the correspondent seamount chains. Noble gases of the low 3He/4He type crusts originate mainly from a HIMU-type lower mantle source contaminated by recycled oceanic crust, whereas noble gases in the high 3He/4He type samples originate mainly from an EM-type lower mantle source contaminated by recycled sediments which captured the air component. The difference in the lower mantle end-member is the fundamental reason results in the differences in the noble gas composition between the two type crusts. The platinum group elements (PGE) contents of crust samples vary from one seamount chain to another and there are significant differentiation between different elements of PGE, indicating the diversity of PGE source of crusts and the variation of the enrichment mechanism in seamount chains. The PGE in crusts origin mainly from alteration of mantle-deirived submarine basalts and river and eolian input, while the contributin of extraterrestrial material is limited. This proves the mantle origin hypotheses of noble gases in ferromanganese crusts. The study of low-temperature alteration and the mass balance theoretical calculation of oceanic island basalts (OIB) indicate that low-temperature alteration of OIB can supply abundant amount of metals to seawater and OIB play as an important source of transition metals for the formation of ferromanganese crusts.
页数176
语种中文
文献类型学位论文
条目标识符http://ir.qdio.ac.cn/handle/337002/773
专题海洋环流与波动重点实验室
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卜文瑞. 太平洋富钴结壳稀有气体地球化学特征及其成矿指示意义[D]. 海洋研究所. 中国科学院海洋研究所,2008.
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