The inhibition of mild steel corrosion in 1 M hydrochloric acid solutions by triazole derivative
Xu, Fengling1,2; Duan, Jizhou1; Zhang, Shufang1,2; Hou, Baorong1
2008-09-30
发表期刊MATERIALS LETTERS
ISSN0167-577X
卷号62期号:25页码:4072-4074
文章类型Article
摘要The title compound 1-(4,5-dihydro-3-phenylpyridine-1-yl)-2-(1H-1,2,4-triazole-1-yl)ethyl ketone (DTE) was synthesized and its inhibiting action on the corrosion of mild steel in 1 M hydrochloric acid solutions was investigated by means of weight loss, potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and scanning electronic microscope (SEM). Results obtained revealed that DIE performed excellently as a corrosion inhibitor for mild steel in 1 M hydrochloric acid media and its efficiency attains more than 90.9% at 1.0 x 10(-3) M at 298 K. Polarization curves indicated that the inhibitor behave mainly as mixed-type inhibitor. EIS showed that the charge transfer controls the corrosion process in the uninhibited and inhibited solutions. Adsorption of the inhibitor on the mild steel surface followed Langmuir adsorption isotherm. And the values of the free energy of adsorption Delta G(ads) indicated that the adsorption of DTE molecule was a spontaneous process and was typical of chemisorption. (c) 2008 Elsevier B.V. All rights reserved.; The title compound 1-(4,5-dihydro-3-phenylpyridine-1-yl)-2-(1H-1,2,4-triazole-1-yl)ethyl ketone (DTE) was synthesized and its inhibiting action on the corrosion of mild steel in 1 M hydrochloric acid solutions was investigated by means of weight loss, potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and scanning electronic microscope (SEM). Results obtained revealed that DIE performed excellently as a corrosion inhibitor for mild steel in 1 M hydrochloric acid media and its efficiency attains more than 90.9% at 1.0 x 10(-3) M at 298 K. Polarization curves indicated that the inhibitor behave mainly as mixed-type inhibitor. EIS showed that the charge transfer controls the corrosion process in the uninhibited and inhibited solutions. Adsorption of the inhibitor on the mild steel surface followed Langmuir adsorption isotherm. And the values of the free energy of adsorption Delta G(ads) indicated that the adsorption of DTE molecule was a spontaneous process and was typical of chemisorption. (c) 2008 Elsevier B.V. All rights reserved.
关键词Corrosion Metals And Alloys Triazole-type Compound Inhibition Hydrochloric Acid
学科领域Materials Science, Multidisciplinary ; Physics, Applied
DOI10.1016/j.matlet.2008.05.037
URL查看原文
收录类别SCI
语种英语
WOS记录号WOS:000258966300004
引用统计
被引频次:76[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.qdio.ac.cn/handle/337002/5150
专题海洋环境腐蚀与生物污损重点实验室
作者单位1.Chinese Acad Sci, Inst Oceanol, Qingdao 266071, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
第一作者单位中国科学院海洋研究所
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GB/T 7714
Xu, Fengling,Duan, Jizhou,Zhang, Shufang,et al. The inhibition of mild steel corrosion in 1 M hydrochloric acid solutions by triazole derivative[J]. MATERIALS LETTERS,2008,62(25):4072-4074.
APA Xu, Fengling,Duan, Jizhou,Zhang, Shufang,&Hou, Baorong.(2008).The inhibition of mild steel corrosion in 1 M hydrochloric acid solutions by triazole derivative.MATERIALS LETTERS,62(25),4072-4074.
MLA Xu, Fengling,et al."The inhibition of mild steel corrosion in 1 M hydrochloric acid solutions by triazole derivative".MATERIALS LETTERS 62.25(2008):4072-4074.
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