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Binuclear Cobalt(II) Complex and Cobalt(II) Coordination Polymer of Bidentate Ligand 1,3-Bis(2-benzimidazolyl)benzene: Crystal Structures and Magnetic Properties
Liu Fa-Qian1; Zhao Jie2; Zhang Dong3; Duan Xiao-Quan3; Wang Lei1; Deng Yue-Yi3; Li Wei-Hua2
2015-07-10
Source PublicationCHINESE JOURNAL OF INORGANIC CHEMISTRY
Volume31Issue:7Pages:1402-1408
SubtypeArticle
AbstractTwo cobalt(II) complexes, Co-2(MBimB)(2)Cl-4 center dot 2H(2)O center dot EDA (1) (MBimB=1,3-bis(2-benzimidazolyl)benzene, EDA=ethylenediamine) and [Co(MBimB)Cl-2], (2), have been synthesized based on the rigid ligand MBimB and characterized by single crystal X-ray diffraction. In complex 1, two MBimB molecules adopt "cis" conformation and bridge two cobalt(I) ions to form a binuclear metallaycyclic framework. In complex 2, MBimB ligand adopts "trans" conformation and bridges two adjacent cobalt(II) ions into 1D zigzag chain. Magnetic susceptibility of 1 and 2 showed ferromagnetic coupling firstly and then antiferromagnetic coupling as the temperature decreases. Compared to complex 2, stronger ferromagnetic interaction and/or spin-orbital coupling between the cobalt(I) ions in 1 can be ascribed to the shorter distance of Co center dot center dot center dot Co and enhanced intervening aromatic pi-system between the metal centers. CCDC: 993989, 1; 993990, 2.
KeywordCoordination Polymer 1 Binuclear Cobalt(Ii) Complex 3-bis(2-benzimidazolyl)Benzene Magnetic Properties
Indexed BySCI
Language英语
WOS IDWOS:000358634000018
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Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.qdio.ac.cn/handle/337002/49611
Collection海洋环境腐蚀与与生物污损重点实验室
Affiliation1.Qingdao Univ Sci & Technol, Minist Educ, Engn Res Ctr High Performance Polymer & Molding T, Qingdao 266042, Shandong, Peoples R China
2.Chinese Acad Sci, Inst Oceanol, Qingdao 266071, Shandong, Peoples R China
3.Guilin Med Univ, Coll Pharm, Guilin 541004, Guangxi, Peoples R China
Recommended Citation
GB/T 7714
Liu Fa-Qian,Zhao Jie,Zhang Dong,et al. Binuclear Cobalt(II) Complex and Cobalt(II) Coordination Polymer of Bidentate Ligand 1,3-Bis(2-benzimidazolyl)benzene: Crystal Structures and Magnetic Properties[J]. CHINESE JOURNAL OF INORGANIC CHEMISTRY,2015,31(7):1402-1408.
APA Liu Fa-Qian.,Zhao Jie.,Zhang Dong.,Duan Xiao-Quan.,Wang Lei.,...&Li Wei-Hua.(2015).Binuclear Cobalt(II) Complex and Cobalt(II) Coordination Polymer of Bidentate Ligand 1,3-Bis(2-benzimidazolyl)benzene: Crystal Structures and Magnetic Properties.CHINESE JOURNAL OF INORGANIC CHEMISTRY,31(7),1402-1408.
MLA Liu Fa-Qian,et al."Binuclear Cobalt(II) Complex and Cobalt(II) Coordination Polymer of Bidentate Ligand 1,3-Bis(2-benzimidazolyl)benzene: Crystal Structures and Magnetic Properties".CHINESE JOURNAL OF INORGANIC CHEMISTRY 31.7(2015):1402-1408.
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