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| Synthesis, crystal structure and electrochemical studies of catena-poly([bis(1-vinyl-1H-imidazole-kN(3))copper(II)]-mu-phthalato-k(2) O : O ') | |
| Li Shao-Xiang1; Zhao Guang-Fa1; Liu Fa-Qian1; Huang Zhao-Ge1; Li Wei-Hua2; Liu Guang-Ye1 | |
| 2008-09-01 | |
| 发表期刊 | CHINESE JOURNAL OF CHEMISTRY
 |
| 卷号 | 26期号:9页码:1732-1736 |
| 文章类型 | Article |
| 摘要 | The crystal of [Cu(pa)(vim)(2)](n) (where pa=phthalic acid dianion, vim= 1-vinyl-1H-imidazole) was synthesized and its structure was characterized by X-ray single crystal diffractometry and elemental analysis. It crystallizes in monoclinic system, C2/c space group with the cell parameters of a=1.6527(3) nm, b=0.81800(16) nm, c= 1.4463(3) nm, beta = 113.19(3)degrees, V= 1.7973(7) nm(3), Z=4, and D(c)= 1.537 g.cm(-3). Final R indices [I>2 sigma(I)] are: R(1) = 0.0476, wR(2)=0.1235 while R indices for all data are: R(1)=0.0693. wR(2)=0.1355. The title compound exhibits an existence of polymeric zigzag chains extended along c-axis. Each Cu(II) ion is located at a crystallographic center of symmetry being coordinated by two N and two O atoms in a distorted square-planar geometry. The electrochemical studies reveal that redox of Cu(2+)/Cu(+) is a quasi-reversible one-electron process. |
| 关键词 | Phthalate Compound Cu(Ii) Carboxylate Crystal Structure Cyclic Voltammetry |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000259664300035 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.qdio.ac.cn/handle/337002/32628 |
| 专题 | 海洋环境腐蚀与生物污损重点实验室 |
| 作者单位 | 1.Qingdao Univ Sci & Technol, Key Lab Adv Mat, Qingdao 266042, Shandong, Peoples R China 2.Chinese Acad Sci, Inst Oceanol, Qingdao 266042, Shandong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li Shao-Xiang,Zhao Guang-Fa,Liu Fa-Qian,et al. Synthesis, crystal structure and electrochemical studies of catena-poly([bis(1-vinyl-1H-imidazole-kN(3))copper(II)]-mu-phthalato-k(2) O : O ')[J]. CHINESE JOURNAL OF CHEMISTRY,2008,26(9):1732-1736. |
| APA | Li Shao-Xiang,Zhao Guang-Fa,Liu Fa-Qian,Huang Zhao-Ge,Li Wei-Hua,&Liu Guang-Ye.(2008).Synthesis, crystal structure and electrochemical studies of catena-poly([bis(1-vinyl-1H-imidazole-kN(3))copper(II)]-mu-phthalato-k(2) O : O ').CHINESE JOURNAL OF CHEMISTRY,26(9),1732-1736. |
| MLA | Li Shao-Xiang,et al."Synthesis, crystal structure and electrochemical studies of catena-poly([bis(1-vinyl-1H-imidazole-kN(3))copper(II)]-mu-phthalato-k(2) O : O ')".CHINESE JOURNAL OF CHEMISTRY 26.9(2008):1732-1736. |
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