Enhanced photoelectrochemical cathodic protection performance of H2O2-treated In2O3 thin-film photoelectrode under visible light
Sun, Mengmeng; Chen, Zhuoyuan; Bu, Yuyu
2015-03-25
发表期刊SURFACE & COATINGS TECHNOLOGY
卷号266页码:79-87
文章类型Article
摘要In this work, a H2O2-treated indium oxide (In2O3) semiconductor material was prepared. The photoelectrochemical cathodic protection performance and the photoelectrochemical behaviors of the H2O2-treated In2O3 were investigated. Under visible light illumination, the H2O2-treated In2O3 exhibits enhanced photoelectrochemical conversion efficiency ( the photoinduced current density was increased by approximately 50%) and enhanced photoelectrochemical cathodic protection performance (the photoinduced cathodic protection current density was increased by approximately 81.8%). The concentrations of adsorbed oxygen and oxygen vacancy in In2O3 were increased after H2O2 treatment, resulting in the enhancement of visible light absorption activity of the H2O2-treated In2O3. With the increase of the concentration of oxygen vacancy, the Fermi level of In2O3 negatively shifts, which promotes the photoelectrochemical cathodic protection performance of the H2O2-treated In2O3. The increased surface adsorbed oxygen groups is beneficial for capturing the photoinduced electrons, resulting in the promotion of the separation efficiency of the photogenerated electron-hole pairs and the electron transfer capability, and hence leading to the increase of the photoelectrochemical cathodic protection performance of the H2O2-treated In2O3. (C) 2015 Published by Elsevier B.V.
关键词Photoelectrochemical Cathodic Protection Indium Oxide Visible Light Adsorbed Oxygen Oxygen Vacancy H2o2 Treatment
DOI10.1016/j.surfcoat.2015.02.023
收录类别SCI
语种英语
WOS记录号WOS:000352664600012
引用统计
被引频次:27[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.qdio.ac.cn/handle/337002/25472
专题海洋环境腐蚀与生物污损重点实验室
作者单位Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, Qingdao 266071, Peoples R China
第一作者单位中国科学院海洋研究所
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Sun, Mengmeng,Chen, Zhuoyuan,Bu, Yuyu. Enhanced photoelectrochemical cathodic protection performance of H2O2-treated In2O3 thin-film photoelectrode under visible light[J]. SURFACE & COATINGS TECHNOLOGY,2015,266:79-87.
APA Sun, Mengmeng,Chen, Zhuoyuan,&Bu, Yuyu.(2015).Enhanced photoelectrochemical cathodic protection performance of H2O2-treated In2O3 thin-film photoelectrode under visible light.SURFACE & COATINGS TECHNOLOGY,266,79-87.
MLA Sun, Mengmeng,et al."Enhanced photoelectrochemical cathodic protection performance of H2O2-treated In2O3 thin-film photoelectrode under visible light".SURFACE & COATINGS TECHNOLOGY 266(2015):79-87.
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