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Varioxepine A, a 3H-Oxepine-Containing Alkaloid with a New Oxa-Cage from the Marine Algal-Derived Endophytic Fungus Paecilomyces variotii
Zhang, Peng1,2; Mandi, Attila3; Li, Xiao-Ming1; Du, Feng-Yu1; Wang, Jia-Ning1,2; Li, Xin1,2; Kurtan, Tibor3; Wang, Bin-Gui1; Kurtan, T (reprint author), Debrecen Univ Med, Dept Organ Chem, POB 20, H-4010 Debrecen, Hungary.
2014-09-19
发表期刊ORGANIC LETTERS
卷号16期号:18页码:4834-4837
文章类型Article
摘要A new 3H-oxepine-containing alkaloid, varioxepine A (1), characterized by a structurally unprecedented condensed 3,6,8-trioxabicyclo[3.2.1]octane motif, was isolated from the marine algal-derived endophytic fungus Paecilomyces variotii. Due to the low proton/carbon ratio, the unambiguous assignment of the planar structure and relative configuration was precluded by NMR experiments and solved by single crystal X-ray analysis. The absolute configuration was established by DFT conformational analysis and TDDFT-ECD calculations. Compound 1 inhibited plant pathogenic fungus Fusarium graminearum.
学科领域Chemistry
DOI10.1021/ol502329k
收录类别SCI ; IC
语种英语
WOS记录号WOS:000342117600036
引用统计
被引频次:38[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.qdio.ac.cn/handle/337002/24191
专题实验海洋生物学重点实验室
通讯作者Kurtan, T (reprint author), Debrecen Univ Med, Dept Organ Chem, POB 20, H-4010 Debrecen, Hungary.
作者单位1.Chinese Acad Sci, Inst Oceanol, Key Lab Expt Marine Biol, Qingdao 266071, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Debrecen Univ Med, Dept Organ Chem, H-4010 Debrecen, Hungary
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GB/T 7714
Zhang, Peng,Mandi, Attila,Li, Xiao-Ming,et al. Varioxepine A, a 3H-Oxepine-Containing Alkaloid with a New Oxa-Cage from the Marine Algal-Derived Endophytic Fungus Paecilomyces variotii[J]. ORGANIC LETTERS,2014,16(18):4834-4837.
APA Zhang, Peng.,Mandi, Attila.,Li, Xiao-Ming.,Du, Feng-Yu.,Wang, Jia-Ning.,...&Kurtan, T .(2014).Varioxepine A, a 3H-Oxepine-Containing Alkaloid with a New Oxa-Cage from the Marine Algal-Derived Endophytic Fungus Paecilomyces variotii.ORGANIC LETTERS,16(18),4834-4837.
MLA Zhang, Peng,et al."Varioxepine A, a 3H-Oxepine-Containing Alkaloid with a New Oxa-Cage from the Marine Algal-Derived Endophytic Fungus Paecilomyces variotii".ORGANIC LETTERS 16.18(2014):4834-4837.
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