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题名: Varioxepine A, a 3H-Oxepine-Containing Alkaloid with a New Oxa-Cage from the Marine Algal-Derived Endophytic Fungus Paecilomyces variotii
作者: Zhang Peng(张鹏)1,2; Mandi, Attila3; Li, Xiao-Ming1; Du, Feng-Yu1; Wang JiaNing(王佳宁)1,2; Li, Xin1,2; Kurtan, Tibor3; Wang, BinGui(王斌贵)1
刊名: ORGANIC LETTERS
出版日期: 2014-09-19
卷号: 16, 期号:18, 页码:4834-4837
学科分类: Chemistry
DOI: 10.1021/ol502329k
通讯作者: Kurtan, T (reprint author), Debrecen Univ Med, Dept Organ Chem, POB 20, H-4010 Debrecen, Hungary.
文章类型: Article
英文摘要: A new 3H-oxepine-containing alkaloid, varioxepine A (1), characterized by a structurally unprecedented condensed 3,6,8-trioxabicyclo[3.2.1]octane motif, was isolated from the marine algal-derived endophytic fungus Paecilomyces variotii. Due to the low proton/carbon ratio, the unambiguous assignment of the planar structure and relative configuration was precluded by NMR experiments and solved by single crystal X-ray analysis. The absolute configuration was established by DFT conformational analysis and TDDFT-ECD calculations. Compound 1 inhibited plant pathogenic fungus Fusarium graminearum.
收录类别: SCI ; IC
语种: 英语
WOS记录号: WOS:000342117600036
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.qdio.ac.cn/handle/337002/24191
Appears in Collections:实验海洋生物学重点实验室_期刊论文

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作者单位: 1.Chinese Acad Sci, Inst Oceanol, Key Lab Expt Marine Biol, Qingdao 266071, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Debrecen Univ Med, Dept Organ Chem, H-4010 Debrecen, Hungary
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文件名: Varioxepine A, a 3H-Oxepine-Containing Alkaloid with a New Oxa-Cage from the Marine Algal-Derived Endophytic Fungus Paecilomyces variotii.pdf
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