Super-hydrophobic metal-complex film fabricated electrochemically on copper as a barrier to corrosive medium
Wang, Peng1; Zhang, Dun1; Qiu, Ri1,2; Wu, Jiajia1,2; Zhang, D (reprint author), Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, 7 Naihai Rd, Qingdao 266071, Peoples R China.
2014-06-01
发表期刊CORROSION SCIENCE
卷号83页码:317-326
文章类型Article
摘要Metal-complex film with super-hydrophobic property is fabricated on copper (Cu) surface with one-step electrochemical method in laurylamine/ethanol solution. "Dissolution-coordination-precipitation" model is proposed to illuminate formation mechanism of Cu(II)-laurylamine complex film. The super-hydrophobic film can act as a barrier to corrosion of underlying copper with inhibition efficiency close to 100%, and it maintains stability within a wide potential range. The origin of such corrosion protection property is explained from view point that hierarchical micro-structure of the super-hydrophobic film can maintain a stable air/liquid interface which inhibits erosion of corrosive medium. (c) 2014 Elsevier Ltd. All rights reserved.
关键词Copper Sem Eis Interfaces
学科领域Materials Science ; Metallurgy & Metallurgical Engineering
DOI10.1016/j.corsci.2014.02.028
收录类别SCI
语种英语
WOS记录号WOS:000335274700033
引用统计
被引频次:111[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.qdio.ac.cn/handle/337002/23889
专题海洋环境腐蚀与生物污损重点实验室
通讯作者Zhang, D (reprint author), Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, 7 Naihai Rd, Qingdao 266071, Peoples R China.
作者单位1.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, Qingdao 266071, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China
第一作者单位中国科学院海洋研究所
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Wang, Peng,Zhang, Dun,Qiu, Ri,et al. Super-hydrophobic metal-complex film fabricated electrochemically on copper as a barrier to corrosive medium[J]. CORROSION SCIENCE,2014,83:317-326.
APA Wang, Peng,Zhang, Dun,Qiu, Ri,Wu, Jiajia,&Zhang, D .(2014).Super-hydrophobic metal-complex film fabricated electrochemically on copper as a barrier to corrosive medium.CORROSION SCIENCE,83,317-326.
MLA Wang, Peng,et al."Super-hydrophobic metal-complex film fabricated electrochemically on copper as a barrier to corrosive medium".CORROSION SCIENCE 83(2014):317-326.
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