Role of Polyaniline on the Photocatalytic Degradation and Stability Performance of the Polyaniline/Silver/Silver Phosphate Composite under Visible Light
Bu, Yuyu; Chen, Zhuoyuan; Chen, ZY (reprint author), Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, 7 Nanhai Rd, Qingdao 266071, Peoples R China.
2014-10-22
发表期刊ACS APPLIED MATERIALS & INTERFACES
卷号6期号:20页码:17589-17598
文章类型Article
摘要Polyaniline/silver/silver phosphate (PANI/Ag/Ag3PO4) composite was prepared by in situ depositing silver phosphate (Ag3PO4) nanoparticles on the surface of polyaniline (PANI). The best photocatalytic Rhodamine B degradation performance is obtained by the 20 wt % PANI/Ag/Ag3PO4 composite, which is approximately 4 times higher than that of pure Ag3PO4. Meanwhile, the photocatalytic stability of Ag3PO4 is significantly improved by introducing PANI into the PANI/Ag/Ag3PO4 composite. The dramatic promotion of the photocatalytic degradation performance and the photocatalytic stability can be attributed to the formation of a heterojunction electric field between PANI and Ag3PO4, which is approximately 90 mV and points from Ag3PO4 to PANI. The existence of this electric field can dramatically enhance the separation efficiency of the photogenerated electron-hole pairs, accelerate the transfer of photogenerated holes from Ag3PO4 to PANI and therefore inhibit the self-oxidation of Ag3PO4.
关键词Silver Phosphate Polyaniline Heterojunction Photocatalytic Stability Visible Light
学科领域Science & Technology - Other Topics ; Materials Science
DOI10.1021/am503578s
收录类别SCI
语种英语
WOS记录号WOS:000343684200032
引用统计
被引频次:146[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.qdio.ac.cn/handle/337002/23886
专题海洋环境腐蚀与生物污损重点实验室
通讯作者Chen, ZY (reprint author), Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, 7 Nanhai Rd, Qingdao 266071, Peoples R China.
作者单位Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, Qingdao 266071, Peoples R China
第一作者单位中国科学院海洋研究所
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Bu, Yuyu,Chen, Zhuoyuan,Chen, ZY . Role of Polyaniline on the Photocatalytic Degradation and Stability Performance of the Polyaniline/Silver/Silver Phosphate Composite under Visible Light[J]. ACS APPLIED MATERIALS & INTERFACES,2014,6(20):17589-17598.
APA Bu, Yuyu,Chen, Zhuoyuan,&Chen, ZY .(2014).Role of Polyaniline on the Photocatalytic Degradation and Stability Performance of the Polyaniline/Silver/Silver Phosphate Composite under Visible Light.ACS APPLIED MATERIALS & INTERFACES,6(20),17589-17598.
MLA Bu, Yuyu,et al."Role of Polyaniline on the Photocatalytic Degradation and Stability Performance of the Polyaniline/Silver/Silver Phosphate Composite under Visible Light".ACS APPLIED MATERIALS & INTERFACES 6.20(2014):17589-17598.
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