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Heterometallic copper(II) vanadates: synthesis, crystal structures and third-order nonlinear optical properties | |
Liu FaQian1; Wang Lei1; Guo JiXi2; Li WeiHua3,4; Li ChaoQin1; Jin YanLing1; Li RongXun1; Jian FangFang1; Liu, FQ (reprint author), Qingdao Univ Sci & Technol, Engn Res Ctr High Performance Polymer Molding Tec, Minist Educ, Qingdao 266042, Peoples R China. | |
2014-09-01 | |
发表期刊 | SCIENCE CHINA-CHEMISTRY |
卷号 | 57期号:9页码:1235-1245 |
文章类型 | Article |
摘要 | Three polymeric heterometallic clusters with 1D, 2D, and 3D frameworks, constructed from a cyclic vanadate {V4O12}(4-) building block and three geometric constraint ligands, were synthesized by a one-pot self-assembly reaction. Z-scan experiments demonstrated that all the three cluster polymers have large hyperpolarizability gamma values. TD-DFT calculations afforded insight into the electronic transitions and spectral characterization of these novel NLO molecular materials. |
关键词 | Cluster Polymers Third-order Nonlinear Optical Properties Td-dft Calculations Polyoxovanadate |
学科领域 | Chemistry |
DOI | 10.1007/s11426-014-5080-4 |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000341094200008 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.qdio.ac.cn/handle/337002/23877 |
专题 | 海洋环境腐蚀与生物污损重点实验室 |
通讯作者 | Liu, FQ (reprint author), Qingdao Univ Sci & Technol, Engn Res Ctr High Performance Polymer Molding Tec, Minist Educ, Qingdao 266042, Peoples R China. |
作者单位 | 1.Qingdao Univ Sci & Technol, Engn Res Ctr High Performance Polymer Molding Tec, Minist Educ, Qingdao 266042, Peoples R China 2.Xinjiang Univ, Inst Appl Chem, Urumqi 830046, Peoples R China 3.Chinese Acad Sci, Inst Oceanol, Qingdao 266071, Peoples R China 4.Collaborat Innovat Ctr Engn Construct & Safety Oc, Qingdao 266033, Peoples R China |
推荐引用方式 GB/T 7714 | Liu FaQian,Wang Lei,Guo JiXi,et al. Heterometallic copper(II) vanadates: synthesis, crystal structures and third-order nonlinear optical properties[J]. SCIENCE CHINA-CHEMISTRY,2014,57(9):1235-1245. |
APA | Liu FaQian.,Wang Lei.,Guo JiXi.,Li WeiHua.,Li ChaoQin.,...&Liu, FQ .(2014).Heterometallic copper(II) vanadates: synthesis, crystal structures and third-order nonlinear optical properties.SCIENCE CHINA-CHEMISTRY,57(9),1235-1245. |
MLA | Liu FaQian,et al."Heterometallic copper(II) vanadates: synthesis, crystal structures and third-order nonlinear optical properties".SCIENCE CHINA-CHEMISTRY 57.9(2014):1235-1245. |
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