Fabrication of robust, durable and integrated Janus coating for corrosion and fouling protection in marine environment

doi:10.1016/j.porgcoat.2023.108152

	Fabrication of robust, durable and integrated Janus coating for corrosion and fouling protection in marine environment
	Yuan, Shuai1,2 ; Zhao, Xia1,3 ; Jin, Zuquan 3; Deng, Junying 4; Zhang, Hui1,2 ; Wu, Siwei 1,2,5; Duan, Jizhou 1; Greenfield, Donald Terry 1; Hou, Baorong 1
	2024-02-01
发表期刊	PROGRESS IN ORGANIC COATINGS
ISSN	0300-9440
卷号	187 页码:16
通讯作者	Zhao, Xia(zx@qdio.ac.cn) ; Hou, Baorong(brhou@qdio.ac.cn)
摘要	Janus membranes with different valuable characteristics and integrated structures have attracted a great interest of researches in order to achieve important breakthroughs in the related fields. However, the application of Janus membranes for development of anticorrosion coatings on metallic structures has been limited, which is due to weak interfacial bonding within the Janus structure and its vulnerability to damage. To address the aforementioned drawbacks, a novel strategy based on multifunction Janus membranes is presented. In this research, the steel is coated with polyurethane, followed by electrospinning a coating composed of polyurethane nanofibers with kaolin nanoparticles, and finally coated with epoxy resin containing modified ZnO to obtain the Janus membrane. The interface of the Janus membrane is accompanied by covalent bonds, leading to 10-fold enhancement in interface adhesion compared to the resin coating. The obtained Janus coating has a top surface that is superhydrophobic and a bottom surface that is hydrophilic, with excellent antiwetting and antibacterial properties. Moreover, the Janus coating shows outstanding barrier properties and the corresponding impedance modulus is maintained about 109 omega center dot cm2 after 75 immersion days. Notably, the coating surface has retained superhydrophobicity after abrasion test with 600-grit sandpaper under a load of 1000 g for 60 m distance. The antibacterial tests have shown the Janus coating could decrease the bacterial coverage on the surface by 25 %. This study has revealed the potential of the Janus electrofibrous membrane as directly coatings on the metallic substrates for the first time, and in this way, multifunction coating with corrosion and fouling protection performances has been achieved.
关键词	Janus membranes Electrospinning Multifunctional coatings Anticorrosion Antibacterial Mechanical durability
DOI	10.1016/j.porgcoat.2023.108152
收录类别	SCI
语种	英语
资助项目	Chinese National Science Foundation[52278286] ; Chinese National Science Foundation[U2106221] ; Chinese National Science Foundation[52225905] ; Shandong Province Central Guidance Science and Technology Development Fund[YDZX 20203700002831] ; Wenhai Program of the S & T Fund of Shandong Province for Pilot Qingdao National Laboratory for Marine Science and Technology[2021WHZZB2304] ; Shandong Key Laboratory of Corrosion Science
WOS研究方向	Chemistry ; Materials Science
WOS类目	Chemistry, Applied ; Materials Science, Coatings & Films
WOS记录号	WOS:001146823700001
出版者	ELSEVIER SCIENCE SA
WOS关键词	SUPERHYDROPHOBIC SURFACE ; OXIDE NANOPARTICLES ; IN-SITU ; ANTICORROSION ; GRAPHENE ; ANTIBACTERIAL ; COMPOSITES ; ADSORPTION ; RESISTANCE ; MEMBRANES
引用统计
文献类型	期刊论文
条目标识符	http://ir.qdio.ac.cn/handle/337002/184360
专题	海洋环境腐蚀与生物污损重点实验室
通讯作者	Zhao, Xia; Hou, Baorong
作者单位	1.Chinese Acad Sci, Inst Oceanol, CAS Key Lab Marine Environm Corros & Biofouling, Qingdao 266071, Peoples R China 2.Univ Chinese Acad Sci, 19 Jia Yuquan Rd, Beijing 100049, Peoples R China 3.Qingdao Univ Technol, Cooperat Innovat Ctr Engn Construction & Safety Sh, Qingdao 266032, Peoples R China 4.Wanhua Chem Grp Co Ltd, Yantai 264000, Peoples R China 5.Chinese Acad Sci, South China Sea Inst Oceanol, 164 Xingangxi Rd, Guangzhou 510301, Peoples R China
第一作者单位	中国科学院海洋研究所
通讯作者单位	中国科学院海洋研究所
推荐引用方式 GB/T 7714	Yuan, Shuai,Zhao, Xia,Jin, Zuquan,et al. Fabrication of robust, durable and integrated Janus coating for corrosion and fouling protection in marine environment[J]. PROGRESS IN ORGANIC COATINGS,2024,187:16.
APA	Yuan, Shuai.,Zhao, Xia.,Jin, Zuquan.,Deng, Junying.,Zhang, Hui.,...&Hou, Baorong.(2024).Fabrication of robust, durable and integrated Janus coating for corrosion and fouling protection in marine environment.PROGRESS IN ORGANIC COATINGS,187,16.
MLA	Yuan, Shuai,et al."Fabrication of robust, durable and integrated Janus coating for corrosion and fouling protection in marine environment".PROGRESS IN ORGANIC COATINGS 187(2024):16.