Construction of a high-performance anti-corrosion epoxy coating in the presence of poly(aniline-co-pyrrole) nanospheres

doi:10.1016/j.reactfunctpolym.2023.105794

	Construction of a high-performance anti-corrosion epoxy coating in the presence of poly(aniline-co-pyrrole) nanospheres
	Mirzaee, Majid 1; Kianpour, Effat 2; Rashidi, Alimorad 3; Rahimi, Alireza 4; Pourhashem, Sepideh 5,6,7; Duan, Jizhou 5,6,7; Iravani, Danial 8; Gohari, Maryam Sirati 3
	2024
发表期刊	REACTIVE & FUNCTIONAL POLYMERS
ISSN	1381-5148
卷号	194 页码:15
通讯作者	Rashidi, Alimorad(rashidiam@ripi.ir)
摘要	Since corrosion with its direct and indirect negative effects is a global issue, coatings are commonly used as a structural corrosion protection strategy. The reinforcement effects of Poly (aniline-co-pyrrole) (PACP) nanospheres on corrosion resistance of solvent-based epoxy coatings are investigated in this study. The corrosion behavior of mild steel substrates coated with epoxy containing different weight percents (0.25, 0.5, 0.75, and 1.0 wt%) of PACP nanospheres is investigated using electrochemical impedance spectroscopy (EIS) in a 3.5 wt% NaCl solution, while the fracture cross-section is studied by field emission scanning electron microscopy (FESEM). The incorporation of the PACP nanospheres in the polymer coatings considerably improves the protective performance of the epoxy coatings. The results of the EIS test shows that the highest corrosion resistance is for the EP-PACP- 0.75 wt% sample. In the first day of immersion, \|Z\|100kHz is equal to 5.2 x 1012 omega.cm2, which is much more than the pure epoxy sample (105 omega.cm2). After two months of immersion, the resistance reduction for the optimum sample is negligible and the amount of water uptake into the coating is the lowest. These findings demonstrate that the epoxy/PACP nanocomposite is superior when compared to the pure epoxy coating.
关键词	Poly(aniline co -pyrrole) Nanospheres Epoxy Nanocomposite coatings Corrosion protection
DOI	10.1016/j.reactfunctpolym.2023.105794
收录类别	SCI
语种	英语
资助项目	Research Institute of Petroleum Industry (RIPI) , INSF's Project[99010368] ; Ministry of Science and Technology Program for Young Foreign Talents[133137KYSB20200034] ; CAS-VPST Silk Road Science Fund 2021 ; [QN2022055002L]
WOS研究方向	Chemistry ; Engineering ; Polymer Science
WOS类目	Chemistry, Applied ; Engineering, Chemical ; Polymer Science
WOS记录号	WOS:001127619500001
出版者	ELSEVIER
WOS关键词	CORROSION PROTECTION PROPERTIES ; NANOCOMPOSITE COATINGS ; CONDUCTING POLYMERS ; STEEL ; POLYPYRROLE ; POLYANILINE ; INHIBITORS ; FILMS
引用统计	被引频次：2[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.qdio.ac.cn/handle/337002/184255
专题	海洋环境腐蚀与生物污损重点实验室
通讯作者	Rashidi, Alimorad
作者单位	1.Niroo Res Inst, Nonmet Mat Res Grp, POB 14665517, Tehran, Iran 2.Univ Mazandaran, Fac Chem, Dept Phys Chem, POB 47416-9544, Babolsar, Iran 3.Res Inst Petr Ind RIPI, Nanotechnol Res Ctr, POB 14857-33111,West Entrance Blvd,Olymp Village, Tehran, Iran 4.Res Inst Petr Ind RIPI, Res & Dev Energy & Environm, POB 14857-33111,West Entrance Blvd,Olymp Village, Tehran, Iran 5.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, 7 Nanhai Rd, Qingdao 266071, Peoples R China 6.Pilot Natl Lab Marine Sci & Technol Qingdao, Open studio marine Corros & Protect, 1 Wenhai Rd, Qingdao 266237, Peoples R China 7.Chinese Acad Sci, Ctr Ocean Mega Sci, 7 Nanhai Rd, Qingdao 266071, Peoples R China 8.Univ Mashhad, Fac Engn, Chem Engn Dept, Mashhad, Iran
推荐引用方式 GB/T 7714	Mirzaee, Majid,Kianpour, Effat,Rashidi, Alimorad,et al. Construction of a high-performance anti-corrosion epoxy coating in the presence of poly(aniline-co-pyrrole) nanospheres[J]. REACTIVE & FUNCTIONAL POLYMERS,2024,194:15.
APA	Mirzaee, Majid.,Kianpour, Effat.,Rashidi, Alimorad.,Rahimi, Alireza.,Pourhashem, Sepideh.,...&Gohari, Maryam Sirati.(2024).Construction of a high-performance anti-corrosion epoxy coating in the presence of poly(aniline-co-pyrrole) nanospheres.REACTIVE & FUNCTIONAL POLYMERS,194,15.
MLA	Mirzaee, Majid,et al."Construction of a high-performance anti-corrosion epoxy coating in the presence of poly(aniline-co-pyrrole) nanospheres".REACTIVE & FUNCTIONAL POLYMERS 194(2024):15.