Anti-corrosion and anti-fouling properties of ball-like GQDs hybrided MOFs functionalized with silane in waterborne epoxy-polydimethylsiloxane coatings: Experimental and theoretical studies

doi:10.1016/j.apmt.2022.101704

	Anti-corrosion and anti-fouling properties of ball-like GQDs hybrided MOFs functionalized with silane in waterborne epoxy-polydimethylsiloxane coatings: Experimental and theoretical studies
	Zhou, Ziyang 1,2,3; Seif, Abdolvahab 5; Pourhashem, Sepideh 1,4,6; Duan, Jizhou 1,4,6; Rashidi, Alimorad 7; Mirzaee, Majid 8; Silvestrelli, Pier Luigi 5; Hou, Baorong 1,4,6
	2023-02-01
发表期刊	APPLIED MATERIALS TODAY
ISSN	2352-9407
卷号	30 页码:16
通讯作者	Duan, Jizhou(duanjz@qdio.ac.cn) ; Rashidi, Alimorad(rashidiam@ripi.ir)
摘要	In this research, two strategies including epoxy matrix modification with 3-aminopropyltriethoxy silane (APTES) and polydimethylsiloxane (PDMS) as well as loading APTES-modified hybrids of graphene quantum dots and metal-organic framework (F-GQDs@MOF) are used to gain a composite epoxy coating with advance resistance against corrosion and fouling on Q235 steel structures. The X-ray analysis of diffraction and photoelectron spectroscopy, Fourier transform infrared spectroscopy, and morphology monitoring by transmission electron microscopy indicate that the GQDs are inserted inside the MOF structure through the in situ reaction, and the hybrid is successfully functionalized with the silane alkoxides. The EP-PDMS/F-GQDs@MOF composite coating shows high water contact angle (more than 100 degrees), low surface roughness, high adhesion strength (8.5 MPa which is 2 times more than the EP-PDMS), superior electrochemical resistance (more than 108 omega.cm2 which is com-parable with EP-PDMS sample with 106 omega.cm2 impedance modulus after immersion in the NaCl solution for 60 days), and negligible corrosion products and blisters after salt spray test. Moreover, the achieved data by the density functional theory (DFT) method show that the functionalization of the GQDs affects remarkably the strengthening of the interface between this moiety and the MOF in such a way to retard the electrochemical reactions. Besides, the results of immersion in Qingdao port reveal that negligible amounts of marine organisms have covered the surface of the EP-PDMS/F-GQDs@MOF sample, while Styela clava and Botrylloides sp. are attached on the EP-PDMS surface. The antibacterial activity of the EP-PDMS/F-GQDs@MOF against Pseudomonas sp. is proved by low attached bacteria on its surface.
关键词	Graphene quantum dots Metal-organic frameworks Hybrids Corrosion and fouling resistant waterborne epoxies Density functional theory
DOI	10.1016/j.apmt.2022.101704
收录类别	SCI
语种	英语
资助项目	Key Research Program of Frontier Sciences-CAS[ZDBS-LY-DQC025] ; INSF's Project[99010368] ; Ministry of Science and Technology Program for Young Foreign Talents[QN2022055002L] ; CAS-VPST Silk Road Science Fund 2021[133137KYSB20200034]
WOS研究方向	Materials Science
WOS类目	Materials Science, Multidisciplinary
WOS记录号	WOS:000908385500001
出版者	ELSEVIER
WOS关键词	NANOCOMPOSITE COATINGS ; QUANTUM-DOT ; PERFORMANCE ; PDMS ; FABRICATION ; FRAMEWORKS ; OXIDATION ; EFFICIENT ; TOLUENE ; FACILE
引用统计	被引频次：8[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.qdio.ac.cn/handle/337002/183285
专题	海洋环境腐蚀与生物污损重点实验室
通讯作者	Duan, Jizhou; Rashidi, Alimorad
作者单位	1.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, 7 Nanhai Rd, Qingdao 266071, Peoples R China 2.Univ Sydney, Australian Ctr Microscopy & Microanal, Sydney, NSW, Australia 3.Univ Chinese Acad Sci, 19 Jia Yuquan Rd, Beijing 100049, Peoples R China 4.Pilot Natl Lab Marine Sci & Technol Qingdao, Open Studio Marine Corros & Protect, 1 Wenhai Rd, Qingdao 266237, Peoples R China 5.Univ Padua, Dipartimento Fis & Astron G Galilei, Via Marzolo 8, I-35131 Padua, Italy 6.Chinese Acad Sci, Ctr Ocean Mega Sci, 7 Nanhai Rd, Qingdao 266071, Peoples R China 7.Res Inst Petr Ind RIPI, Nanotechnol Res Ctr, West Entrance Blvd,POB 14857-33111, Tehran 33111, Iran 8.Niroo Res Inst, Nonmet Mat Res Grp, Tehran 14665517, Iran
第一作者单位	中国科学院海洋研究所
通讯作者单位	中国科学院海洋研究所
推荐引用方式 GB/T 7714	Zhou, Ziyang,Seif, Abdolvahab,Pourhashem, Sepideh,et al. Anti-corrosion and anti-fouling properties of ball-like GQDs hybrided MOFs functionalized with silane in waterborne epoxy-polydimethylsiloxane coatings: Experimental and theoretical studies[J]. APPLIED MATERIALS TODAY,2023,30:16.
APA	Zhou, Ziyang.,Seif, Abdolvahab.,Pourhashem, Sepideh.,Duan, Jizhou.,Rashidi, Alimorad.,...&Hou, Baorong.(2023).Anti-corrosion and anti-fouling properties of ball-like GQDs hybrided MOFs functionalized with silane in waterborne epoxy-polydimethylsiloxane coatings: Experimental and theoretical studies.APPLIED MATERIALS TODAY,30,16.
MLA	Zhou, Ziyang,et al."Anti-corrosion and anti-fouling properties of ball-like GQDs hybrided MOFs functionalized with silane in waterborne epoxy-polydimethylsiloxane coatings: Experimental and theoretical studies".APPLIED MATERIALS TODAY 30(2023):16.