1D Bi2S3 nanorods modified 2D BiOI nanoplates for highly efficient photocatalytic activity: Pivotal roles of oxygen vacancies and Z-scheme heterojunction

doi:10.1016/j.jmst.2022.09.037

	1D Bi2S3 nanorods modified 2D BiOI nanoplates for highly efficient photocatalytic activity: Pivotal roles of oxygen vacancies and Z-scheme heterojunction
	Ju, Peng1,2,3 ; Zhang, Yu1 ; Hao, Lei 1,4; Cao, Jiazhen 1; Zhai, Xiaofan3 ; Dou, Kunpeng 5; Jiang, Fenghua 1; Sun, Chengjun 1,2
	2023-04-10
发表期刊	JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
ISSN	1005-0302
卷号	142 页码:45-59
通讯作者	Ju, Peng(jupeng@fio.org.cn) ; Sun, Chengjun(csun@fio.org.cn)
摘要	In this study, a novel Bi2S3/BiOI Z-scheme photocatalyst with 3D porous hierarchical network-like het-erostructure (BSBI NHs) and rich oxygen vacancies (OVs) was fabricated by a facile ion exchange method followed by the in-situ growth process. A possible formation mechanism of BSBI NHs was studied, show-ing the self-assembled process of in-situ interwoven growth of 1D Bi2S3 nanorods (NRs) on the surface of 2D BiOI disk-like nanoplates (NPs), which followed the Ostwald ripening and epitaxial growth. The mod-ification of BiOI NPs by Bi2S3 NRs brought about the formation of Z-scheme heterojunction and massive OVs, which improved the visible-light response property and promoted the separation of photoexcited charge carriers of BSBI NHs. BSBI NHs exhibited a significantly enhanced photocatalytic activity compared with Bi2S3 and BiOI, and BSBI-1 can remove almost all bacteria and Rhodamine B (RhB) after 60 min vis-ible light illumination. In addition, the photocatalytic mechanism was studied and speculated based on the tests of active species capture, electron spin resonance (ESR), and density functional theory (DFT) simulation calculation, proving the primary roles of center dot OH, middotO 2 - and h + during the photocatalytic reaction. This work provides new insights into the design and exploitation of novel heterojunctions with highly efficient photocatalytic performances for environmental remediation applications.(c) 2022 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.
关键词	Antifouling Photocatalysis BiOI Biofouling
DOI	10.1016/j.jmst.2022.09.037
收录类别	SCI
语种	英语
资助项目	Basic Scientific Fund for National Public Research Institutes of China[2020S02] ; Basic Scientific Fund for National Public Research Institutes of China[2019Y03] ; National Natural Science Foundation of China[51702328] ; Key Research and Development Program of Shandong Province (Major Scientific and Technological Innovation Project)[2019JZZY020711] ; Young Elite Scientists Spon-sorship Program by CAST[YESS20210201]
WOS研究方向	Materials Science ; Metallurgy & Metallurgical Engineering
WOS类目	Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
WOS记录号	WOS:000891067100005
出版者	JOURNAL MATER SCI TECHNOL
引用统计	被引频次：12[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.qdio.ac.cn/handle/337002/180986
专题	海洋环境腐蚀与生物污损重点实验室
通讯作者	Ju, Peng; Sun, Chengjun
作者单位	1.Minist Nat Resources, Inst Oceanog 1, Marine Bioresource & Environm Res Ctr, Key Lab Marine Ecoenvironm Sci & Technol, Qingdao 266061, Peoples R China 2.Pilot Natl Lab Marine Sci & Technol Qingdao, Lab Marine Drugs & Bioprod, Qingdao 266237, Peoples R China 3.Chinese Acad Sci, Inst Oceanol, CAS Key Lab Marine Environm Corros & Biofouling, Qingdao 266071, Peoples R China 4.Taiyuan Univ Technol, Coll Chem Engn & Technol, Dept Chem Prod Engn, Taiyuan 030024, Peoples R China 5.Ocean Univ China, Coll Informat Sci & Engn, Qingdao 266100, Peoples R China
第一作者单位	中国科学院海洋研究所
通讯作者单位	中国科学院海洋研究所
推荐引用方式 GB/T 7714	Ju, Peng,Zhang, Yu,Hao, Lei,et al. 1D Bi2S3 nanorods modified 2D BiOI nanoplates for highly efficient photocatalytic activity: Pivotal roles of oxygen vacancies and Z-scheme heterojunction[J]. JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,2023,142:45-59.
APA	Ju, Peng.,Zhang, Yu.,Hao, Lei.,Cao, Jiazhen.,Zhai, Xiaofan.,...&Sun, Chengjun.(2023).1D Bi2S3 nanorods modified 2D BiOI nanoplates for highly efficient photocatalytic activity: Pivotal roles of oxygen vacancies and Z-scheme heterojunction.JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,142,45-59.
MLA	Ju, Peng,et al."1D Bi2S3 nanorods modified 2D BiOI nanoplates for highly efficient photocatalytic activity: Pivotal roles of oxygen vacancies and Z-scheme heterojunction".JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY 142(2023):45-59.

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