Institutional Repository of Key Laboratory of Marine Environmental Corrosion and Bio-fouling, IOCAS
| Environmentally benign smart self-healing silicone-based coating with dual antifouling and anti-corrosion properties | |
Sun, Jiawen1,2,3,4; Duan, Jizhou1,2,3,4; Liu, Xiangju1,2,4; Dong, Xucheng1,2,3,4 ; Zhang, Yimeng1,2,4; Liu, Chao1,5; Hou, Baorong1,2,3,4
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| 2022-08-01 | |
| Source Publication | APPLIED MATERIALS TODAY
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| ISSN | 2352-9407 |
| Volume | 28Pages:19 |
| Corresponding Author | Duan, Jizhou(duanjz@qdio.ac.cn) ; Liu, Chao(liuchao@hunau.edu.cn) |
| Abstract | Marine corrosion and biofouling on metallic materials are sticky problems in maintenance of various vessels and facilities in the ocean. Further, designing of an eco-friendly marine coating with both antifouling and anticorrosion properties has remained a significant challenge in marine field. The present study aimed to develop a novel smart self-healing silicone-based coating with dual antifouling and anti-corrosion properties was through disulfide exchange reaction between the functionalized monomer "lipoic acid-benzothiazole" (LA-BTZ) and LA modified polydimethylsiloxane (PDMS) based polyurea-urethane (PDMS-PUU-LA). Multiple dynamic bonds in backbone, flexible disulfide bonds, and strong cross-linked hydrogen bonds ensure the PDMS-based polymer with good toughness (2.58 MPa of ultimate strength), high stretchability (1014.7%), and self-healing properties. It was found that the scratches on the film in air completely disappeared within 40 min at room temperature. The time required for the healing efficiency of strength ranged between 98.5 and 94.6% under ambient condition and artificial seawater was only 4 and 8 h, respectively. The adhesion strength of silicon-based coating to epoxy resin and steel substrate was -2.50 and -3.33 MPa, respectively. In addition, results of laboratory bioassays and marine field test of 120-day demonstrated that coating without any additional toxic biocides in the present study had long-term static fouling-resistant properties. Electrochemical impedance spectroscopy (EIS) measurements and salt spray test showed that the PDMS-PUU-TZ-3 coating exhibited the better corrosion resistance. Therefore, the current work presented a novel eco-friendly smart silicone-based coating for marine antifouling and anticorrosion. |
| Keyword | Self-healing Hydrogen bonding Disulfide bond Antifouling Anti-corrosion |
| DOI | 10.1016/j.apmt.2022.101551 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | Basic Frontier Science Research Program of Chinese Academy of Sciences[ZDBS-LY-DQC025] ; National Natural Science Foundation of China[41706080] ; Shandong Key Laboratory of Corrosion Science |
| WOS Research Area | Materials Science |
| WOS Subject | Materials Science, Multidisciplinary |
| WOS ID | WOS:000812689100001 |
| Publisher | ELSEVIER |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.qdio.ac.cn/handle/337002/179537 |
| Collection | 海洋环境腐蚀与生物污损重点实验室 |
| Corresponding Author | Duan, Jizhou; Liu, Chao |
| Affiliation | 1.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, 7 Nanhai Rd, Qingdao 266071, Peoples R China 2.Pilot Natl Lab Marine Sci & Technol Qingdao, Open Studio Marine Corros & Protect, 168 Wenhai Middle Rd, Qingdao 266237, Peoples R China 3.Univ Chinese Acad Sci, 19 Jia Yuquan Rd, Beijing 100039, Peoples R China 4.Chinese Acad Sci, Ctr Ocean Mega Sci, 7 Nanhai Rd, Qingdao 266071, Peoples R China 5.Hunan Agr Univ, Coll Resources & Environm, 1 Nongda Rd, Changsha 410128, Peoples R China |
| First Author Affilication | Institute of Oceanology, Chinese Academy of Sciences |
| Corresponding Author Affilication | Institute of Oceanology, Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Sun, Jiawen,Duan, Jizhou,Liu, Xiangju,et al. Environmentally benign smart self-healing silicone-based coating with dual antifouling and anti-corrosion properties[J]. APPLIED MATERIALS TODAY,2022,28:19. |
| APA | Sun, Jiawen.,Duan, Jizhou.,Liu, Xiangju.,Dong, Xucheng.,Zhang, Yimeng.,...&Hou, Baorong.(2022).Environmentally benign smart self-healing silicone-based coating with dual antifouling and anti-corrosion properties.APPLIED MATERIALS TODAY,28,19. |
| MLA | Sun, Jiawen,et al."Environmentally benign smart self-healing silicone-based coating with dual antifouling and anti-corrosion properties".APPLIED MATERIALS TODAY 28(2022):19. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 1-s2.0-S235294072200（33856KB） | 期刊论文 | 出版稿 | 延迟开放 | CC BY-NC-SA | View 2023-7-1后可获取 | |
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