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Removal Study of Crystal Violet and Methylene Blue From Aqueous Solution by Activated Carbon Embedded Zero-Valent Iron: Effect of Reduction Methods
Wang, Yongmei1; Chen, Tiantian2; Zhang, Xiaolin3; Mwamulima, Teza3
2021-12-21
发表期刊FRONTIERS IN ENVIRONMENTAL SCIENCE
卷号9页码:13
通讯作者Chen, Tiantian(chentian0819@163.com)
摘要Zero valent iron (ZVI) particles were embedded into porous materials to avoid aggregation and separation problems in the controlled synthesis process. To investigate the adsorption mechanism of crystal violet and methylene blue, activated carbon (AC) and AC-based ZVI extraction by solid-phase and liquid-phase reduced approaches was conducted. Characterization methods of specific surface area, scanning electron microscopy (SEM), and x-ray diffractograms (XRD) were used to elucidate the structure of adsorbents, and the adsorption capacities of crystal violet and methylene blue were obtained under experimental conditions of various pH values (2.0-10.0), adsorption times (0-72 h), and temperatures (30-50 degrees C). The adsorption of crystal violet/methylene blue was controlled by both chemisorption and reduction. The adsorption processes were fitted to a pseudo-second-order kinetic model, and that of reduction kinetics was suitable to pseudo-first-order kinetic model. The thermodynamic study revealed that the adsorption of crystal violet and methylene blue was endothermic and spontaneous, and the adsorption isotherms fitted well to the Langmuir model. Different adsorption capacities of crystal violet and methylene blue on various adsorbents were found, indicating that both the properties of adsorbents (pore size, specific surface area, and chemical functional groups) and the structures of adsorbates had significant effect on the removal of dye molecules.
关键词water pollution activated carbon zero valent iron crystal violet methylene blue
DOI10.3389/fenvs.2021.799264
收录类别SCI
语种英语
WOS研究方向Environmental Sciences & Ecology
WOS类目Environmental Sciences
WOS记录号WOS:000739077500001
出版者FRONTIERS MEDIA SA
引用统计
被引频次:7[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.qdio.ac.cn/handle/337002/177660
专题海洋生态与环境科学重点实验室
通讯作者Chen, Tiantian
作者单位1.Shandong Univ Sci & Technol, Coll Safety & Environm Engn, Qingdao, Peoples R China
2.Chinese Acad Sci, Inst Oceanol, CAS Key Lab Marine Ecol & Environm Sci, Qingdao, Peoples R China
3.Ocean Univ China, Coll Environm Sci & Engn, Qingdao, Peoples R China
通讯作者单位中国科学院海洋研究所
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Wang, Yongmei,Chen, Tiantian,Zhang, Xiaolin,et al. Removal Study of Crystal Violet and Methylene Blue From Aqueous Solution by Activated Carbon Embedded Zero-Valent Iron: Effect of Reduction Methods[J]. FRONTIERS IN ENVIRONMENTAL SCIENCE,2021,9:13.
APA Wang, Yongmei,Chen, Tiantian,Zhang, Xiaolin,&Mwamulima, Teza.(2021).Removal Study of Crystal Violet and Methylene Blue From Aqueous Solution by Activated Carbon Embedded Zero-Valent Iron: Effect of Reduction Methods.FRONTIERS IN ENVIRONMENTAL SCIENCE,9,13.
MLA Wang, Yongmei,et al."Removal Study of Crystal Violet and Methylene Blue From Aqueous Solution by Activated Carbon Embedded Zero-Valent Iron: Effect of Reduction Methods".FRONTIERS IN ENVIRONMENTAL SCIENCE 9(2021):13.
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