Developing wide pH-responsive, self-healing, and anti-corrosion epoxy composite coatings based on encapsulating oleic acid/ 2-mercaptobenzimidazole corrosion inhibitors in chitosan/poly(vinyl alcohol) core-shell nanofibers

doi:10.1016/j.porgcoat.2021.106454

	Developing wide pH-responsive, self-healing, and anti-corrosion epoxy composite coatings based on encapsulating oleic acid/ 2-mercaptobenzimidazole corrosion inhibitors in chitosan/poly(vinyl alcohol) core-shell nanofibers
	Ji, Xiaohong 1,2,4; Wang, Wei 2,3; Duan, Jizhou 1,2,4; Zhao, Xia1,2,4 ; Wang, Lifei 1,2,4; Wang, Yanli 5; Zhou, Ziyang 1,2,4; Li, Weihua 1,2,4,5; Hou, Baorong 1,2,4,5
	2021-12-01
发表期刊	PROGRESS IN ORGANIC COATINGS
ISSN	0300-9440
卷号	161 页码:13
通讯作者	Wang, Wei(wangwei8038@ouc.edu.cn) ; Duan, Jizhou(duanjz@qdio.ac.cn) ; Zhao, Xia(zx@qdio.ac.cn)
摘要	In this research, the oleic acid (OA) and 2-mercaptobenzimidazole (MBI) encapsulated in the chitosan/poly(vinyl alcohol) (CS/PVA) core-shell nanofibers are synthesized and used for developing core-shell/epoxy composite coatings on Q235 steel substrate to enhance the service-life of coating systems. The results indicate the successful preparation of the CS/PVA core-shell nanofibers loaded with corrosion inhibitors. The corrosion protection performance of the composite coatings are evaluated by electrochemical impedance spectroscopy, revealing that the maximum inhibition efficiency of OA and MBI is 96.66% and 99.36% after 10 and 20 days immersion in alkaline and acidic electrolyte, respectively. Furthermore, the formation of a self-healing film over the metallic substrate after immersion in corrosive electrolyte is confirmed. The synergistic effect of chitosan protonation and MBI corrosion inhibitor makes the composite coating have high corrosion inhibition efficiency in acidic electrolyte. This pH-responsive self-healing approach is potentially useful for designing next-generation of selfhealing coatings with high healing efficiency.
关键词	pH-responsive Chitosan core-shell nanofibers Epoxy composite coatings Self-healing Synergistic effect
DOI	10.1016/j.porgcoat.2021.106454
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[42076039] ; National Natural Science Foundation of China[51708541] ; National Natural Science Foundation of China[51801035] ; Applied Basic Research Programs of Qingdao[E1KY12106N] ; China Postdoctoral Science Foundation[2021M693206] ; CAS-VPST Silk Road Science Fund 2021[133137KYSB20200034] ; Natural Science Foundation of Guangxi Province[2018GXNSFBA138059]
WOS研究方向	Chemistry ; Materials Science
WOS类目	Chemistry, Applied ; Materials Science, Coatings & Films
WOS记录号	WOS:000701917200011
出版者	ELSEVIER SCIENCE SA
引用统计	被引频次：27[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.qdio.ac.cn/handle/337002/176504
专题	海洋环境腐蚀与生物污损重点实验室
通讯作者	Wang, Wei; Duan, Jizhou; Zhao, Xia
作者单位	1.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, Qingdao 266071, Peoples R China 2.Pilot Natl Lab Marine Sci & Technol, Open Studio Marine Corros & Protect, Qingdao 266237, Peoples R China 3.Ocean Univ China, Sch Mat Sci & Engn, 238 Songling Rd, Qingdao 266100, Peoples R China 4.Chinese Acad Sci, Ctr Ocean Megasci, Qingdao 266071, Peoples R China 5.Guangxi Univ, Sch Chem & Chem Engn, Nanning 530004, Peoples R China
第一作者单位	中国科学院海洋研究所; 中国科学院海洋大科学研究中心
通讯作者单位	中国科学院海洋研究所; 中国科学院海洋大科学研究中心
推荐引用方式 GB/T 7714	Ji, Xiaohong,Wang, Wei,Duan, Jizhou,et al. Developing wide pH-responsive, self-healing, and anti-corrosion epoxy composite coatings based on encapsulating oleic acid/ 2-mercaptobenzimidazole corrosion inhibitors in chitosan/poly(vinyl alcohol) core-shell nanofibers[J]. PROGRESS IN ORGANIC COATINGS,2021,161:13.
APA	Ji, Xiaohong.,Wang, Wei.,Duan, Jizhou.,Zhao, Xia.,Wang, Lifei.,...&Hou, Baorong.(2021).Developing wide pH-responsive, self-healing, and anti-corrosion epoxy composite coatings based on encapsulating oleic acid/ 2-mercaptobenzimidazole corrosion inhibitors in chitosan/poly(vinyl alcohol) core-shell nanofibers.PROGRESS IN ORGANIC COATINGS,161,13.
MLA	Ji, Xiaohong,et al."Developing wide pH-responsive, self-healing, and anti-corrosion epoxy composite coatings based on encapsulating oleic acid/ 2-mercaptobenzimidazole corrosion inhibitors in chitosan/poly(vinyl alcohol) core-shell nanofibers".PROGRESS IN ORGANIC COATINGS 161(2021):13.

条目包含的文件
文件名称/大小	文献类型	版本类型	开放类型	使用许可
1-s2.0-S030094402100（5119KB）	期刊论文	出版稿	限制开放	CC BY-NC-SA	浏览