IOCAS-IR  > 海洋环境腐蚀与与生物污损重点实验室
Recent Progress of Electrochemical Production of Hydrogen Peroxide by Two-Electron Oxygen Reduction Reaction
Wang, Nan1,2,3; Ma, Shaobo4; Zuo, Pengjian4; Duan, Jizhou1,2,3; Hou, Baorong1,2,3
2021-05-27
Source PublicationADVANCED SCIENCE
Pages26
Corresponding AuthorMa, Shaobo(shaobomahit@gmail.com) ; Zuo, Pengjian(zuopj@hit.edu.cn) ; Duan, Jizhou(duanjz@qdio.ac.cn)
AbstractShifting electrochemical oxygen reduction reaction (ORR) via two-electron pathway becomes increasingly crucial as an alternative/green method for hydrogen peroxide (H2O2) generation. Here, the development of 2e(-) ORR catalysts in recent years is reviewed, in aspects of reaction mechanism exploration, types of high-performance catalysts, factors to influence catalytic performance, and potential applications of 2e(-) ORR. Based on the previous theoretical and experimental studies, the underlying 2e(-) ORR catalytic mechanism is firstly unveiled, in aspect of reaction pathway, thermodynamic free energy diagram, limiting potential, and volcano plots. Then, various types of efficient catalysts for producing H2O2 via 2e(-) ORR pathway are summarized. Additionally, the catalytic active sites and factors to influence catalysts' performance, such as electronic structure, carbon defect, functional groups (O, N, B, S, F etc.), synergistic effect, and others (pH, pore structure, steric hindrance effect, etc.) are discussed. The H2O2 electrogeneration via 2e(-) ORR also has various potential applications in wastewater treatment, disinfection, organics degradation, and energy storage. Finally, potential future directions and prospects in 2e(-) ORR catalysts for electrochemically producing H2O2 are examined. These insights may help develop highly active/selective 2e(-) ORR catalysts and shape the potential application of this electrochemical H2O2 producing method.
Keywordapplication catalytic mechanism electrochemical catalysts hydrogen peroxide two‐ electron oxygen reduction reaction
DOI10.1002/advs.202100076
Indexed BySCI
Language英语
Funding ProjectKey Research Program of Frontier Sciences, Chinese Academy of Sciences[ZDBS-LY-DQC025] ; National Natural Science Foundation of China[41827805] ; Shandong Key Laboratory of Corrosion Science ; University of Chinese Academy of Sciences (UCAS)
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Materials Science
WOS SubjectChemistry, Multidisciplinary ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS IDWOS:000655406800001
PublisherWILEY
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.qdio.ac.cn/handle/337002/171011
Collection海洋环境腐蚀与与生物污损重点实验室
Corresponding AuthorMa, Shaobo; Zuo, Pengjian; Duan, Jizhou
Affiliation1.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, Qingdao 266071, Peoples R China
2.Chinese Acad Sci, Ctr Ocean Megasci, 7 Nanhai Rd, Qingdao 266071, Peoples R China
3.Pilot Natl Lab Marine Sci & Technol Qingdao, Open Studio Marine Corros & Protect, 1 Wenhai Rd, Qingdao 266237, Peoples R China
4.Harbin Inst Technol, Sch Chem & Chem Engn, MITT Key Lab Crit Mat Technol New Energy Convers, Harbin 150001, Peoples R China
First Author AffilicationInstitute of Oceanology, Chinese Academy of Sciences;  Center for Ocean Mega-Science, Chinese Academy of Sciences
Corresponding Author AffilicationInstitute of Oceanology, Chinese Academy of Sciences;  Center for Ocean Mega-Science, Chinese Academy of Sciences
Recommended Citation
GB/T 7714
Wang, Nan,Ma, Shaobo,Zuo, Pengjian,et al. Recent Progress of Electrochemical Production of Hydrogen Peroxide by Two-Electron Oxygen Reduction Reaction[J]. ADVANCED SCIENCE,2021:26.
APA Wang, Nan,Ma, Shaobo,Zuo, Pengjian,Duan, Jizhou,&Hou, Baorong.(2021).Recent Progress of Electrochemical Production of Hydrogen Peroxide by Two-Electron Oxygen Reduction Reaction.ADVANCED SCIENCE,26.
MLA Wang, Nan,et al."Recent Progress of Electrochemical Production of Hydrogen Peroxide by Two-Electron Oxygen Reduction Reaction".ADVANCED SCIENCE (2021):26.
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