IOCAS-IR  > 海洋环境腐蚀与生物污损重点实验室
Scalable, fluorine free and hot water repelling superhydrophobic and superoleophobic coating based on functionalized Al2O3 nanoparticles
Zhang, Binbin1,2,3; Xu, Weichen1,2,3; Zhu, Qingjun1,2,3; Hou, Baorong1,2,3
2021-03-10
Source PublicationJOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
ISSN1005-0302
Volume66Pages:74-81
Corresponding AuthorZhang, Binbin(zhangbinbin11@mails.ucas.ac.cn)
AbstractHot water droplet and oils induced air cushion failure, intensively used fluorine-containing chemicals, tedious preparation process, etc. are the main bottlenecks of the current artificially fabricated superhydrophobic materials, restricting their large-scale production and real-world applications. Herein, a facile, scalable, fluorine-free spray-coating strategy was employed to achieve superhydrophobic and superoleophobic polymerized organosilanes/Al2O3 nanoparticles (POS/Al2O3 NPs) coatings. The POS/Al2O3 NPs coating was achieved through hydrolytic condensation of tetraethyl orthoilicate (TEOS) and hexadecyltrimethoxysilane (HDTMS) in the presence of Al2O3 NPs. A variety of analytical techniques including scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), energy dispersive X-ray photoelectron spectroscopy (EDS) were used to investigate the fabricated coatings. The POS/Al2O3 NPs coating features high contact angle (>158 degrees) and low sliding angle (<5 degrees) for water, glycerol, and ethylene glycol droplets with different surface tensions, verifying both superhydrophobic and superoleophobic properties. Moreover, the coatings present extremely low surface adhesion force, excellent liquid-driven self-cleaning ability, and hot water repellency. The superamphiphobic POS/Al2O3 NPs coating exhibits promising applications in various fields including self-cleaning, corrosion resistance, and preventing scald as this strategy is applicable on various substrates. (C) 2021 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.
KeywordAl2O3 Self-cleaning Surface coating Thermal stability Supehydrophobicity Wettability
DOI10.1016/j.jmst.2020.06.035
Indexed BySCI
Language英语
Funding ProjectNational Natural Science Foundation of China[41806089] ; National Natural Science Foundation of China[41827805]
WOS Research AreaMaterials Science ; Metallurgy & Metallurgical Engineering
WOS SubjectMaterials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
WOS IDWOS:000610200200009
PublisherJOURNAL MATER SCI TECHNOL
Citation statistics
Cited Times:44[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.qdio.ac.cn/handle/337002/170082
Collection海洋环境腐蚀与生物污损重点实验室
Corresponding AuthorZhang, Binbin
Affiliation1.Chinese Acad Sci, Inst Oceanol, CAS Key Lab Marine Environm Corros & Biofouling, Qingdao 266071, Peoples R China
2.Pilot Natl Lab Marine Sci & Technol Qingdao, Open Studio Marine Corros & Protect, Qingdao 266237, Peoples R China
3.Chinese Acad Sci, Ctr Ocean Megasci, Qingdao 266071, Peoples R China
First Author AffilicationInstitute of Oceanology, Chinese Academy of Sciences;  Center for Ocean Mega-Science, Chinese Academy of Sciences
Corresponding Author AffilicationInstitute of Oceanology, Chinese Academy of Sciences;  Center for Ocean Mega-Science, Chinese Academy of Sciences
Recommended Citation
GB/T 7714
Zhang, Binbin,Xu, Weichen,Zhu, Qingjun,et al. Scalable, fluorine free and hot water repelling superhydrophobic and superoleophobic coating based on functionalized Al2O3 nanoparticles[J]. JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,2021,66:74-81.
APA Zhang, Binbin,Xu, Weichen,Zhu, Qingjun,&Hou, Baorong.(2021).Scalable, fluorine free and hot water repelling superhydrophobic and superoleophobic coating based on functionalized Al2O3 nanoparticles.JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,66,74-81.
MLA Zhang, Binbin,et al."Scalable, fluorine free and hot water repelling superhydrophobic and superoleophobic coating based on functionalized Al2O3 nanoparticles".JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY 66(2021):74-81.
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