Effect of nanoscale graphene oxide on the sustained photoelectrochemical cathodic protection performance of the WO3 nanothorn clusters

doi:10.1007/s10800-021-01537-1

	Effect of nanoscale graphene oxide on the sustained photoelectrochemical cathodic protection performance of the WO3 nanothorn clusters
	Sun, Mengmeng 1,2,3; Chen, Zhuoyuan 1,2,3; Jing, Jiangping 1,2,3; Feng, Chang 1,2,3
	2021-02-11
发表期刊	JOURNAL OF APPLIED ELECTROCHEMISTRY
ISSN	0021-891X
页码	14
通讯作者	Chen, Zhuoyuan(zychen@qdio.ac.cn)
摘要	The novel photoelectrochemical cathodic protection technology is actively researched and developed for alleviating severe corrosion of marine metallic materials. And the corresponding sustained photoelectrochemical cathodic protection in the dark, under the collaboration of the electron storage materials, is also developed and optimized. WO3, as a kind of electron storage material, shows great potential in this area. The WO3/graphene oxide (WO3/GO) nanothorn cluster composites were synthesized via solovthermal method. The nanoscale graphene oxide (GO) sheets, added as templates, result in the formation of WO3 nanothorn clusters in the WO3/GO composite. The hybrid structure of the WO3/GO composite was formed when the GO adding amount is 0.2 wt%, denoted as WO3/GO 0.2. The lattice of WO3 contracted slightly and the crystallinity of WO3 was enhanced. The WO3/GO 0.2 nanothorn cluster composites promote the transfer and storage efficiency of the electrons compared with pure WO3. The high conductivity of the partly reduced GO leads to a faster electron transfer in the WO3/GO composite. The sustained photoelectrochemical cathodic protection performance of the WO3/GO composite under the assistance of TiO2 (i.e., the coupling of WO3/GO 0.2-TiO2) for 304 stainless steel (SS) was promoted. A larger number of photoinduced electrons, generated by TiO2 under white light illumination, can be stored in the WO3/GO composite and be transferred to the coupled 304 SS electrode after shutting off the light. [GRAPHICS] .
关键词	WO3 nanothorn clusters Nanoscale graphene oxide Composite materials Electron storage The sustained photoelectrochemical cathodic protection
DOI	10.1007/s10800-021-01537-1
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[41976036] ; National Natural Science Foundation of China[41676069] ; National Natural Science Foundation of China[41906034] ; Key Research and Development Program of Shandong Province[2019GHY112085] ; Key Research and Development Program of Shandong Province[2019GHY112066]
WOS研究方向	Electrochemistry
WOS类目	Electrochemistry
WOS记录号	WOS:000617103900004
出版者	SPRINGER
引用统计	被引频次：4[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.qdio.ac.cn/handle/337002/169743
专题	海洋环境腐蚀与生物污损重点实验室
通讯作者	Chen, Zhuoyuan
作者单位	1.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, 7 Nanhai Rd, Qingdao 266071, Peoples R China 2.Chinese Acad Sci, Ctr Ocean Mega Sci, 7 Nanhai Rd, Qingdao 266071, Peoples R China 3.Pilot Natl Lab Marine Sci & Technol Qingdao, Open Studio Marine Corros & Protect, 1 Wenhai Rd, Qingdao 266237, Peoples R China
第一作者单位	中国科学院海洋研究所
通讯作者单位	中国科学院海洋研究所
推荐引用方式 GB/T 7714	Sun, Mengmeng,Chen, Zhuoyuan,Jing, Jiangping,et al. Effect of nanoscale graphene oxide on the sustained photoelectrochemical cathodic protection performance of the WO3 nanothorn clusters[J]. JOURNAL OF APPLIED ELECTROCHEMISTRY,2021:14.
APA	Sun, Mengmeng,Chen, Zhuoyuan,Jing, Jiangping,&Feng, Chang.(2021).Effect of nanoscale graphene oxide on the sustained photoelectrochemical cathodic protection performance of the WO3 nanothorn clusters.JOURNAL OF APPLIED ELECTROCHEMISTRY,14.
MLA	Sun, Mengmeng,et al."Effect of nanoscale graphene oxide on the sustained photoelectrochemical cathodic protection performance of the WO3 nanothorn clusters".JOURNAL OF APPLIED ELECTROCHEMISTRY (2021):14.

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