Electrochemical detection of hydroquinone and catechol with covalent organic framework modified carbon paste electrode

doi:10.1016/j.jelechem.2020.114530

	Electrochemical detection of hydroquinone and catechol with covalent organic framework modified carbon paste electrode
	Xin, Yu 1,2,3; Wang, Ning 1,2; Wang, Chunli 1,2,4; Gao, Wei 4; Chen, Mingli 4; Liu, Nazhen 1,2; Duan, Jizhou 1,2; Hou, Baorong 1,2
	2020-11-15
发表期刊	JOURNAL OF ELECTROANALYTICAL CHEMISTRY
ISSN	1572-6657
卷号	877 页码:9
通讯作者	Liu, Nazhen(liunazhen@qdio.ac.cn)
摘要	A covalent organic framework (COF) modified carbon paste electrode (CPE) was used for the electrochemical detection of hazardous hydroquinone (HQ) and catechol (CC). Due to the advantages of TpBD-COF (large surface area, abundant functional groups and high chemical stability), rapid quantitative determination of HQ and CC was accomplished by differential pulse voltammetry (DPV). Under the optimal conditions, the resultant sensor showed an extended linear response range for HQ and CC (1-2000 mu mol L-1), and the detection limits were 0.31 and 0.46 mu mol L-1 (S/N = 3) respectively. The simultaneous determination of HQ and CC can be accomplished by data deconvolution. In binary solutions with one constant constituent concentration, a linear relationship was established between the deconvoluted peak current and concentration of the changing constituent. In addition, the electrochemical sensor showed strong anti-interference ability, good reproducibility (a relative standard deviation of 0.99% for HQ and 0.77% for CC, n = 5) and applicability in real sample detection (with spiking recoveries from 97.7%- 101.6% for HQ and 100.3% - 103.3% for CC). These results demonstrate that COF modified carbon materials are promising candidates for efficient electrochemical detection of phenolic compounds.
关键词	Covalent organic framework Carbon paste electrode Hydroquinone Catechol Electrochemical sensor Differential pulse voltammetry
DOI	10.1016/j.jelechem.2020.114530
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[51901222] ; National Natural Science Foundation of China[41827805] ; CAS Pioneer Hundred Talents Program
WOS研究方向	Chemistry ; Electrochemistry
WOS类目	Chemistry, Analytical ; Electrochemistry
WOS记录号	WOS:000588305500015
出版者	ELSEVIER SCIENCE SA
引用统计	被引频次：49[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.qdio.ac.cn/handle/337002/169136
专题	海洋环境腐蚀与生物污损重点实验室
通讯作者	Liu, Nazhen
作者单位	1.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, Qingdao 266071, Peoples R China 2.Pilot Natl Lab Marine Sci & Technol Qingdao, Open Studio Marine Corros & Protect, 1 Wenhai Rd, Qingdao 266237, Peoples R China 3.Univ Chinese Acad Sci, 19 Jia Yuquan Rd, Beijing 100039, Peoples R China 4.Northeastern Univ, Coll Sci, Res Ctr Analyt Sci, Dept Chem, Shenyang 110819, Peoples R China
第一作者单位	中国科学院海洋研究所
通讯作者单位	中国科学院海洋研究所
推荐引用方式 GB/T 7714	Xin, Yu,Wang, Ning,Wang, Chunli,et al. Electrochemical detection of hydroquinone and catechol with covalent organic framework modified carbon paste electrode[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY,2020,877:9.
APA	Xin, Yu.,Wang, Ning.,Wang, Chunli.,Gao, Wei.,Chen, Mingli.,...&Hou, Baorong.(2020).Electrochemical detection of hydroquinone and catechol with covalent organic framework modified carbon paste electrode.JOURNAL OF ELECTROANALYTICAL CHEMISTRY,877,9.
MLA	Xin, Yu,et al."Electrochemical detection of hydroquinone and catechol with covalent organic framework modified carbon paste electrode".JOURNAL OF ELECTROANALYTICAL CHEMISTRY 877(2020):9.

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