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Application of confocal laser Raman spectroscopy on marine sediment microplastics
Liu Jing1,2,4,5; Zhang Xin1,2,3,4,5; Du Zengfeng1,2,5; Luan Zhendong1,2,5; Li Lianfu1,2,4,5; Xi Shichuan1,2,4,5; Wang Bing1,2,5; Cao Lei1,2,5; Yan Jun1,2,5
2020-09-01
发表期刊JOURNAL OF OCEANOLOGY AND LIMNOLOGY
ISSN2096-5508
卷号38期号:5页码:1502-1516
通讯作者Zhang Xin(xzhang@qdio.ac.cn)
摘要Marine sediment is the primary sink of microplastics and is an indicator of pollution levels. However, although there are well-developed detection methods, detection is rarely focused on low-micrometer-sized particles, mainly due to technique limitations. In this study, a simplified process omitting digestion procedures was developed to pretreat microplastics obtained from marine sediment and was coupled with micro-Raman spectroscopy to identify microplastics. Based on the overall analysis of the characteristic peak assignments, a Raman spectral reference library was constructed for 18 types of plastic. In addition, the effects of the measurement parameters were systematically described. Field research was then conducted to validate the developed process and investigate microplastic contamination in Huiquan Bay, Qingdao, China. This simplified process could retain the original appearance of microparticles and accomplish the detection of <500 mu m-sized microplastics in environmental samples. Microplastics in the size range of 10-150 mu m accounted for 76% of all microplastics, and 56% of the total particles was particles smaller than 50 mu m. Polypropylene (42%) and polyethylene (20%) were predominant components of the particles. In particular, polypropylene particles smaller than 10 mu m were identified in marine sediment. This work demonstrates that Raman spectroscopy is not only an effective tool for detecting environmental particles but also highly applicable for identifying particles extracted from marine sediment.
关键词microplastics confocal Raman spectroscopy marine sediment
DOI10.1007/s00343-020-0129-z
收录类别SCI
语种英语
WOS研究方向Marine & Freshwater Biology ; Oceanography
WOS类目Limnology ; Oceanography
WOS记录号WOS:000584398800013
出版者SCIENCE PRESS
引用统计
被引频次:15[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.qdio.ac.cn/handle/337002/169097
专题海洋地质与环境重点实验室
通讯作者Zhang Xin
作者单位1.Chinese Acad Sci, Key Lab Marine Geol & Environm, Qingdao 266071, Peoples R China
2.Chinese Acad Sci, Ctr Deep Sea Res, Inst Oceanol, Qingdao 266071, Peoples R China
3.Pilot Natl Lab Marine Sci & Technol Qingdao, Lab Marine Geol, Qingdao 266237, Peoples R China
4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
5.Chinese Acad Sci, Ctr Ocean Mega Sci, Qingdao 266071, Peoples R China
第一作者单位中国科学院海洋研究所
通讯作者单位中国科学院海洋研究所
推荐引用方式
GB/T 7714
Liu Jing,Zhang Xin,Du Zengfeng,et al. Application of confocal laser Raman spectroscopy on marine sediment microplastics[J]. JOURNAL OF OCEANOLOGY AND LIMNOLOGY,2020,38(5):1502-1516.
APA Liu Jing.,Zhang Xin.,Du Zengfeng.,Luan Zhendong.,Li Lianfu.,...&Yan Jun.(2020).Application of confocal laser Raman spectroscopy on marine sediment microplastics.JOURNAL OF OCEANOLOGY AND LIMNOLOGY,38(5),1502-1516.
MLA Liu Jing,et al."Application of confocal laser Raman spectroscopy on marine sediment microplastics".JOURNAL OF OCEANOLOGY AND LIMNOLOGY 38.5(2020):1502-1516.
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