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A silsesquioxane-based flexible polyimide aerogel with high hydrophobicity and good adsorption for liquid pollutants in wastewater
Wu, Yumin1; Qiu, Hui1; Sun, Jiawen2,3; Wang, Yupin1; Gao, Chuanhui1; Liu, Yuetao1
2020-10-22
发表期刊JOURNAL OF MATERIALS SCIENCE
ISSN0022-2461
页码13
通讯作者Liu, Yuetao(yuetaoliu@qust.edu.cn)
摘要A type of silsesquioxane-based flexible polyimide aerogel was synthesized by 3,3 ',4,4 '-benzophenonetetracarboxylic dianhydride (BTDA), 4,4 '-diaminodiphenyl and octa(aminopropylsilsesquioxane) (POSS-NH2) with a facile thermal curing and atmospheric drying process. POSS-NH2 was introduced into the polyimide backbone as a cross-linking agent. The obtained aerogel possessed high hydrophobicity with a water contact angle exceeding 143 degrees. And the aerogels showed good cyclic adsorption capacity for various organic solvents, such as acetone, methanol, ethyl acetate, etc. After 15 adsorption experiments, the original adsorption capacity of the aerogels (more than 3 times their own weight) was still maintained. SEM and BET confirmed that the introduction of POSS-NH2 could form a larger pore structure inside the aerogel, thereby achieving an improvement in adsorption performance. The results indicated this kind of aerogel might be flexibly utilized as adsorbent materials for oil pollutants and harmful organic reagents in the field of wastewater treatment.
DOI10.1007/s10853-020-05460-2
收录类别SCI
语种英语
资助项目Shandong Provincial Natural Science Foundation[ZR2018MB034] ; National Natural Science Foundation of China[51872150] ; Science and technology support plan for Youth Innovation of colleges and universities in Shandong Province[2020KJC005]
WOS研究方向Materials Science
WOS类目Materials Science, Multidisciplinary
WOS记录号WOS:000582363300004
出版者SPRINGER
引用统计
被引频次:7[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.qdio.ac.cn/handle/337002/168969
专题中国科学院海洋研究所
通讯作者Liu, Yuetao
作者单位1.Qingdao Univ Sci & Technol, Coll Chem Engn, State Key Lab Base Ecochem Engn, Qingdao 266042, Peoples R China
2.Chinese Acad Sci, Inst Oceanol, Qingdao 266071, Peoples R China
3.Pilot Natl Lab Marine Sci & Technol Qingdao, Open Studio Marine Corros & Protect, Qingdao 266237, Peoples R China
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GB/T 7714
Wu, Yumin,Qiu, Hui,Sun, Jiawen,et al. A silsesquioxane-based flexible polyimide aerogel with high hydrophobicity and good adsorption for liquid pollutants in wastewater[J]. JOURNAL OF MATERIALS SCIENCE,2020:13.
APA Wu, Yumin,Qiu, Hui,Sun, Jiawen,Wang, Yupin,Gao, Chuanhui,&Liu, Yuetao.(2020).A silsesquioxane-based flexible polyimide aerogel with high hydrophobicity and good adsorption for liquid pollutants in wastewater.JOURNAL OF MATERIALS SCIENCE,13.
MLA Wu, Yumin,et al."A silsesquioxane-based flexible polyimide aerogel with high hydrophobicity and good adsorption for liquid pollutants in wastewater".JOURNAL OF MATERIALS SCIENCE (2020):13.
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