Mechanistic study on initial passivation and surface chemistry of steel bars in nano-silica cement pastes
Zheng, Haibing1; Poon, Chi Sun1; Li, Weihua2,3
2020-09-01
发表期刊CEMENT & CONCRETE COMPOSITES
ISSN0958-9465
卷号112页码:14
摘要This work studied the passivation of steel bar in cement pastes prepared with and without nano-silica by using electrochemical measurements and surface characterization methods. The results showed that the passivation of steel bar in cement paste was dominated by the chemistry of the pore solution and the evolution over time, which are closely associated with the hydration process of the cement. The addition of nano-silica influenced the alkalinity of the pore solution in cement paste and modified the pore structure of the cement paste, which resulted in a different passivation process and a thicker passive film with a higher proportion of Fe2+ oxides. The intrinsic corrosion resistance of steel bars in concrete prepared with nano-silica was expected to be enhanced.
关键词Concrete Steel bar Passivation Corrosion Nano-silica
DOI10.1016/j.cemconcomp.2020.103661
收录类别SCI
语种英语
资助项目Hong Kong Branch of the National Engineering Research Center for Steel Construction ; National Natural Science Fund for Distinguished Young Scholars[51525903]
WOS研究方向Construction & Building Technology ; Materials Science
WOS类目Construction & Building Technology ; Materials Science, Composites
WOS记录号WOS:000556826200013
出版者ELSEVIER SCI LTD
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被引频次:28[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
版本出版稿
条目标识符http://ir.qdio.ac.cn/handle/337002/168115
专题海洋环境腐蚀与生物污损重点实验室
通讯作者Poon, Chi Sun
作者单位1.Hong Kong Polytech Univ, Dept Civil & Environm Engn, Hong Kong, Peoples R China
2.Sun Yat Sen Univ, Coll Chem Engn & Technol, Tangjiawan 519082, Zhuhai, Peoples R China
3.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, Qingdao 266071, Peoples R China
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Zheng, Haibing,Poon, Chi Sun,Li, Weihua. Mechanistic study on initial passivation and surface chemistry of steel bars in nano-silica cement pastes[J]. CEMENT & CONCRETE COMPOSITES,2020,112:14.
APA Zheng, Haibing,Poon, Chi Sun,&Li, Weihua.(2020).Mechanistic study on initial passivation and surface chemistry of steel bars in nano-silica cement pastes.CEMENT & CONCRETE COMPOSITES,112,14.
MLA Zheng, Haibing,et al."Mechanistic study on initial passivation and surface chemistry of steel bars in nano-silica cement pastes".CEMENT & CONCRETE COMPOSITES 112(2020):14.
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