Institutional Repository of Key Laboratory of Marine Environmental Corrosion and Bio-fouling, IOCAS
Exploring the bactericidal performance and application of novel mimic enzyme Co4S3 | |
Wang, Jin1,2,3,4; Wang, Yi1,3,4![]() | |
2020-03-01 | |
Source Publication | JOURNAL OF COLLOID AND INTERFACE SCIENCE
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ISSN | 0021-9797 |
Volume | 561Pages:327-337 |
Corresponding Author | Wang, Yi(wangyi@qdio.ac.cn) ; Zhang, Dun(zhangdun@qdio.ac.cn) |
Abstract | Novel and uniform Co4S3 nanoparticles were synthesized through a two-step hydrothermal process and testified to possess intrinsic peroxidase (POx)-like activity for the first time. As a fresh POx mimic, we studied its catalytic properties, kinetic, and mechanism to catalyze the oxidation of 3, 3', 5, 5'-tetramethylbenzidine in the presence of H2O2. According to the experiments, the bactericidal mechanism is the same as that of simulated enzyme. Based on the ability of Co4S3 inducing H2O2 to express center dot O-2(-), the bactericidal rate can be as high as 100%. Besides, using the POx-like activity of Co4S3, a new off-on sensor for H2O2 and L-cysteine (L-Cys) detection is constructed. The sensor reveals a good wide linear response to H2O2 in the 40-2000 mu M with a detection limit of 18 mu M, while L-Cys in the 20-100 mu M with a detection limit of 10 mM. The proposed method also shows great stability, high selectivity, and excellent practicability. (C) 2019 Elsevier Inc. All rights reserved. |
Keyword | Co4S3 Enzyme mimic Sterilization Hydrogen peroxide L-cysteine Colorimetric detection |
DOI | 10.1016/j.jcis.2019.10.110 |
Indexed By | SCI |
Language | 英语 |
Funding Project | National Key Research and Development Program of China[2016YFC1400605] ; Natured Science Foundation of China[41776090] ; Key Research and Development Program of Shandong Province[2018GHY115038] ; AoShan Talent Program ; Qingdao National Laboratory for Marine Science and Technology ; National Key Research and Development Program of China[2016YFC1400605] ; Natured Science Foundation of China[41776090] ; Key Research and Development Program of Shandong Province[2018GHY115038] ; AoShan Talent Program ; Qingdao National Laboratory for Marine Science and Technology |
WOS Research Area | Chemistry |
WOS Subject | Chemistry, Physical |
WOS ID | WOS:000508752600031 |
Publisher | ACADEMIC PRESS INC ELSEVIER SCIENCE |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.qdio.ac.cn/handle/337002/164434 |
Collection | 海洋环境腐蚀与与生物污损重点实验室 |
Corresponding Author | Wang, Yi; Zhang, Dun |
Affiliation | 1.Chinese Acad Sci, Inst Oceanol, CAS Key Lab Marine Environm Corros & Biofouling, Qingdao 266071, Peoples R China 2.Univ Chinese Acad Sci, 19 Jia Yuquan Rd, Beijing 100039, Peoples R China 3.Qingdao Natl Lab Marine Sci & Technol, Open Studio Marine Corros & Protect, 1 Wenhai Rd, Qingdao 266237, Peoples R China 4.Chinese Acad Sci, Ctr Ocean Megasci, 7 Nanhai Rd, Qingdao 266071, Peoples R China |
First Author Affilication | Institute of Oceanology, Chinese Academy of Sciences; Center for Ocean Mega-Science, Chinese Academy of Sciences |
Corresponding Author Affilication | Institute of Oceanology, Chinese Academy of Sciences; Center for Ocean Mega-Science, Chinese Academy of Sciences |
Recommended Citation GB/T 7714 | Wang, Jin,Wang, Yi,Zhang, Dun. Exploring the bactericidal performance and application of novel mimic enzyme Co4S3[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE,2020,561:327-337. |
APA | Wang, Jin,Wang, Yi,&Zhang, Dun.(2020).Exploring the bactericidal performance and application of novel mimic enzyme Co4S3.JOURNAL OF COLLOID AND INTERFACE SCIENCE,561,327-337. |
MLA | Wang, Jin,et al."Exploring the bactericidal performance and application of novel mimic enzyme Co4S3".JOURNAL OF COLLOID AND INTERFACE SCIENCE 561(2020):327-337. |
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