Effect of Triethanolamine and Chloride Ions on Properties of the Passive Films in Saturated Ca(OH)(2) Solution

	Effect of Triethanolamine and Chloride Ions on Properties of the Passive Films in Saturated Ca(OH)(2) Solution
	Zhao, Xia1 ; Cao, Kun 1; Li, Weihua 1; Jin, Zuquan 2; Hou, Baorong 1; Zhao, X
	2013-06-01
发表期刊	INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
ISSN	1452-3981
卷号	8 期号:6 页码:7948-7958
文章类型	Article
摘要	The influence of triethanolamine and chloride ions on protective ability and semi-conductive performance of the passive films, which formed on carbon steel surface in saturated Ca(OH)(2) solution, were investigated by electrochemical impedance spectroscopy(EIS), Mott-Schottky(M-S) plots as well as polarization curves. Two parameters, film resistance R-f and film capacitance Q(f) were provided by fitting the EIS data with appropriate equivalent circuit. The semiconductor parameter, donor density N-d was characterized by M-S plot. Based on the analysis of R-f, Q(f), N-d in conjuction with point defect model(PDM), the relationship between the film protective ability and its semi-conductive properties were concluded.; The influence of triethanolamine and chloride ions on protective ability and semi-conductive performance of the passive films, which formed on carbon steel surface in saturated Ca(OH)(2) solution, were investigated by electrochemical impedance spectroscopy(EIS), Mott-Schottky(M-S) plots as well as polarization curves. Two parameters, film resistance R-f and film capacitance Q(f) were provided by fitting the EIS data with appropriate equivalent circuit. The semiconductor parameter, donor density N-d was characterized by M-S plot. Based on the analysis of R-f, Q(f), N-d in conjuction with point defect model(PDM), the relationship between the film protective ability and its semi-conductive properties were concluded.
关键词	Carbon Steel Eis Polarization Passive Films
学科领域	Electrochemistry
收录类别	SCI
语种	英语
WOS研究方向	Electrochemistry
WOS类目	Electrochemistry
WOS记录号	WOS:000323546100040
WOS关键词	STAINLESS-STEEL ; IRON ; STABILITY ; CORROSION ; METALS ; MODEL
WOS标题词	Science & Technology ; Physical Sciences
引用统计	被引频次：5[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.qdio.ac.cn/handle/337002/16363
专题	海洋环境腐蚀与生物污损重点实验室海洋地质与环境重点实验室
通讯作者	Zhao, X
作者单位	1.Chinese Acad Sci, Key Lab Corros Sci Shandong Prov, Inst Oceanol, Qingdao 266071, Peoples R China 2.Qingdao Technol Univ, Sch Civil Engn, Qingdao 266071, Peoples R China
第一作者单位	中国科学院海洋研究所
推荐引用方式 GB/T 7714	Zhao, Xia,Cao, Kun,Li, Weihua,et al. Effect of Triethanolamine and Chloride Ions on Properties of the Passive Films in Saturated Ca(OH)(2) Solution[J]. INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE,2013,8(6):7948-7958.
APA	Zhao, Xia,Cao, Kun,Li, Weihua,Jin, Zuquan,Hou, Baorong,&Zhao, X.(2013).Effect of Triethanolamine and Chloride Ions on Properties of the Passive Films in Saturated Ca(OH)(2) Solution.INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE,8(6),7948-7958.
MLA	Zhao, Xia,et al."Effect of Triethanolamine and Chloride Ions on Properties of the Passive Films in Saturated Ca(OH)(2) Solution".INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE 8.6(2013):7948-7958.

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