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| Surface Alloying of a Magnesium Alloy with Zinc Oxide by Taking Advantage of the Permeability of the Magnesium Oxide Film | |
Lu, Dongzhu1,2,3,4; Ma, Xiumin1,2,3,4; Huang, Yanliang1,2,3,4; Ma, Fubin1,2,3,4 ; Duan, Jizhou1,2,3,4; Hou, Baorong1,2,3,4
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| 2019-10-10 | |
| Source Publication | JOURNAL OF PHYSICAL CHEMISTRY C
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| ISSN | 1932-7447 |
| Volume | 123Issue:40Pages:24461-24468 |
| Corresponding Author | Lu, Dongzhu(ldz@qdio.ac.cn) |
| Abstract | MgO films would naturally form on a magnesium alloy matrix in the air. They are loose and porous, and the corrosion resistance of magnesium alloys is limited. Here, we demonstrate that such a loose MgO film is not merely useless in the protection of magnesium alloys, as metallic atoms could penetrate the MgO film to form intermetallic coatings on the magnesium alloy matrix. In this work, utilizing a diffusion source which contains ZnO and NH4Cl, an intermetallic layer was obtained on a magnesium alloy. The morphology and chemical composition of the intermetallic layer and the MgO film were analyzed. Results show that Mg atoms in the magnesium alloy could be utilized as a reductive agent to reduce ZnO into Zn atoms, as reduced Zn atoms are able to penetrate the loose MgO film and form a Zn-rich intermetallic layer on the magnesium alloy matrix. The concept that the MgO film could be utilized as a potential path for the surface alloying of magnesium alloys would not only deepen the understanding of the nature of the MgO film but also illuminate the surface treatment industries which usually remove the MgO film before surface modification of magnesium alloys. |
| DOI | 10.1021/acs.jpcc.9b03839 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | Key Research & Development Program of Shandong Province, P. R. China[2018GSF117039] ; Nantong Science and Technology Development Funds, P. R. China[JC2018114] ; Applied Research Program of Qingdao, P. R China[17-1-1-22-jch] ; National Natural Science Foundation of China[41827805] |
| WOS Research Area | Chemistry ; Science & Technology - Other Topics ; Materials Science |
| WOS Subject | Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
| WOS ID | WOS:000490353900014 |
| Publisher | AMER CHEMICAL SOC |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.qdio.ac.cn/handle/337002/163257 |
| Collection | 海洋环境腐蚀与与生物污损重点实验室 |
| Corresponding Author | Lu, Dongzhu |
| Affiliation | 1.Chinese Acad Sci, Inst Oceanol, CAS Key Lab Marine Environm Corros & Biofouling, Qingdao 266071, Shandong, Peoples R China 2.Pilot Natl Lab Marine Sci & Technol Qingdao, Open Studio Marine Corros & Protect, Qingdao 266237, Shandong, Peoples R China 3.Chinese Acad Sci, Ctr Ocean Mega Sci, Qingdao 266071, Shandong, Peoples R China 4.Inst Oceanol, Res & Dev Ctr Marine Sci & Technol, Nantong 226006, Peoples R China |
| First Author Affilication | Institute of Oceanology, Chinese Academy of Sciences |
| Corresponding Author Affilication | Institute of Oceanology, Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Lu, Dongzhu,Ma, Xiumin,Huang, Yanliang,et al. Surface Alloying of a Magnesium Alloy with Zinc Oxide by Taking Advantage of the Permeability of the Magnesium Oxide Film[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2019,123(40):24461-24468. |
| APA | Lu, Dongzhu,Ma, Xiumin,Huang, Yanliang,Ma, Fubin,Duan, Jizhou,&Hou, Baorong.(2019).Surface Alloying of a Magnesium Alloy with Zinc Oxide by Taking Advantage of the Permeability of the Magnesium Oxide Film.JOURNAL OF PHYSICAL CHEMISTRY C,123(40),24461-24468. |
| MLA | Lu, Dongzhu,et al."Surface Alloying of a Magnesium Alloy with Zinc Oxide by Taking Advantage of the Permeability of the Magnesium Oxide Film".JOURNAL OF PHYSICAL CHEMISTRY C 123.40(2019):24461-24468. |
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