IOCAS-IR  > 海洋地质与环境重点实验室
Abundance and distribution pattern of rare earth elements and yttrium in vitrain band of high-rank coal from the Qinshui basin, northern China
Wang, Xiaomei1; Wang, Xiaoming1; Pan, Zhejun2; Yin, Xuebo3; Chai, Pancun1; Pan, Sidong1; Yang, Qin4
2019-07-15
Source PublicationFUEL
ISSN0016-2361
Volume248Pages:93-103
Corresponding AuthorWang, Xiaomei(xiaomei_wang@cug.edu.cn)
AbstractVitrain bands are clean and contain less ash than the bulk coal. A comprehensive study on rare earth elements and yttrium (REY) in vitrain may provide insights into the REY affinity. In this study, abundance and distribution pattern of REY in bulk coal, vitrain band and HCl-HF demineralized vitrain band was investigated. The coal studied in the present work was low-ash (ash yields ranging from 4.13 to 12.86%, with 8.59% as the average), high-rank (anthracite to semi-anthracite, with volatile matter yields of 7.52-13.42%, 9.58% on average) coal of Permian Shanxi Formation, collected from the Sihe and Zhaozhuang mines, southern Qinshui Basin. The major minerals identified by powder XRD are illite and kaolinite, with small amount of ankerite, chlorite, calcite, siderite and pyrite. In comparison to the bulk coal, vitrain band displays a lower REY content and smaller compositional range. The bulk coal has N-, H- and L-type REY patterns based on Seredin-Dai's classification, while the REY distribution for the vitrain band is commonly characterized by an H-type pattern. Moreover, the La N /Lu N ratio in the vitrain band is usually lower than that in the bulk coal. This probably suggests that the organic component has a higher HREY association than LREY compared to the inorganic part. The limited impact of HCl-HF demineralization on content and distribution pattern of REY in vitrain band probably reflects the weak acid solubility of REY in the vitrain band. The sequential chemical extraction procedure reveals that the clays and the residual organics, which have a stronger association with LREY and HREY respectively, are the dominant carriers of total REY in the studied bulk coals.
KeywordCoal Organic affinity HREY enrichment Vitrain band Sequential chemical extraction procedure Shanxi Formation
DOI10.1016/j.fuel.2019.03.054
Indexed BySCI
Language英语
Funding ProjectNational Natural Science Foundation of China[41572143] ; National Natural Science Foundation of China[41202114] ; National Natural Science Foundation of China[41101098] ; Fundamental Research Funds for the Central Universities, China University of Geosciences (Wuhan)[CUGL170220] ; Postdoctoral Science Foundation of China[2012M521499]
WOS Research AreaEnergy & Fuels ; Engineering
WOS SubjectEnergy & Fuels ; Engineering, Chemical
WOS IDWOS:000463823500011
PublisherELSEVIER SCI LTD
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.qdio.ac.cn/handle/337002/161111
Collection海洋地质与环境重点实验室
Corresponding AuthorWang, Xiaomei
Affiliation1.China Univ Geosci, Minist Educ, Key Lab Tecton & Petr Resources, Wuhan 430074, Hubei, Peoples R China
2.CSIRO, Energy Business Unit, Private Bag 10, Clayton, Vic 3169, Australia
3.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Geol & Environm, Qingdao 266071, Shandong, Peoples R China
4.China Univ Geosci, State Key Lab Geol Proc & Mineral Resources, Wuhan 430074, Hubei, Peoples R China
Recommended Citation
GB/T 7714
Wang, Xiaomei,Wang, Xiaoming,Pan, Zhejun,et al. Abundance and distribution pattern of rare earth elements and yttrium in vitrain band of high-rank coal from the Qinshui basin, northern China[J]. FUEL,2019,248:93-103.
APA Wang, Xiaomei.,Wang, Xiaoming.,Pan, Zhejun.,Yin, Xuebo.,Chai, Pancun.,...&Yang, Qin.(2019).Abundance and distribution pattern of rare earth elements and yttrium in vitrain band of high-rank coal from the Qinshui basin, northern China.FUEL,248,93-103.
MLA Wang, Xiaomei,et al."Abundance and distribution pattern of rare earth elements and yttrium in vitrain band of high-rank coal from the Qinshui basin, northern China".FUEL 248(2019):93-103.
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