Institutional Repository of Key Laboratory of Marine Environmental Corrosion and Bio-fouling, IOCAS
| Strong acid resistance from electrochemical deposition of WO3 on super-hydrophobic CuO-coated copper surface | |
Dou, Wenwen1,2,3; Wang, Peng1; Wu, Jiajia1 ; Gu, Tingyue3; Zhang, Dun1
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| 2018-08-01 | |
| Source Publication | MATERIALS AND CORROSION-WERKSTOFFE UND KORROSION
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| ISSN | 0947-5117 |
| Volume | 69Issue:8Pages:978-984 |
| Corresponding Author | Gu, Tingyue(gu@ohio.edu) ; Zhang, Dun(zhangdun@qdio.ac.cn) |
| Abstract | In marine and industrial environments, salts and aggressive contaminants in water may cause corrosion and degradation, including acid corrosion and erosion. Super-hydrophobic (SH) metal oxide films can keep surfaces dry by expelling water droplets. This inhibits corrosion. However, acid rain can dissolve the metal oxide films. Thus, it is necessary to protect SH films against acid erosion. In this work, a WO3 film was added on top of CuO-coated SH copper surface using electrochemical deposition. The composite SH CuO-WO3 film exhibited a strong acid resistance. After 48h immersion in 0.2N sulfuric acid, the film retained its nearly perfect micro-nano structure with a static water contact angle of 160 +/- 2 degrees. After acid erosion, the corrosion rate in a 3.5% (w/w) NaCl solution was tested using potentiodynamic polarization curves. Its corrosion current density was found to be four orders of magnitude lower compared with CuO-coated copper. This kind of acid resistant SH surfaces with much enhanced ability against atmospheric oxygen corrosion in the presence of salty water have potential applications in marine and other industrial environments. |
| Keyword | acid corrosion chemical etching CuO-WO3 electrochemical deposition super-hydrophobic surface |
| DOI | 10.1002/maco.201709878 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Natural Science Foundation of China[41576079] ; Science & Technology Basic Research Program of Qingdao[15-9-1-31-jch] ; Qingdao National Laboratory for Marine Science and Technology[QNLM2016ORP0413] ; Qingdao National Laboratory for Marine Science and Technology[2017ASTCP-ES02] ; China Scholarship Council ; [MS12015119] ; National Natural Science Foundation of China[41576079] ; Science & Technology Basic Research Program of Qingdao[15-9-1-31-jch] ; Qingdao National Laboratory for Marine Science and Technology[QNLM2016ORP0413] ; Qingdao National Laboratory for Marine Science and Technology[2017ASTCP-ES02] ; China Scholarship Council ; [MS12015119] |
| WOS Research Area | Materials Science ; Metallurgy & Metallurgical Engineering |
| WOS Subject | Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering |
| WOS ID | WOS:000440554900002 |
| Publisher | WILEY-V C H VERLAG GMBH |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.qdio.ac.cn/handle/337002/159690 |
| Collection | 海洋环境腐蚀与与生物污损重点实验室 |
| Corresponding Author | Gu, Tingyue; Zhang, Dun |
| Affiliation | 1.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, 7 Nanhai Rd, Qingdao 266071, Peoples R China 2.Univ Chinese Acad Sci, 19 Jia Yuquan Rd, Beijing 100039, Peoples R China 3.Ohio Univ, Inst Corros & Multiphase Technol, Dept Chem & Biomol Engn, Athens, OH 45701 USA |
| First Author Affilication | Institute of Oceanology, Chinese Academy of Sciences |
| Corresponding Author Affilication | Institute of Oceanology, Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Dou, Wenwen,Wang, Peng,Wu, Jiajia,et al. Strong acid resistance from electrochemical deposition of WO3 on super-hydrophobic CuO-coated copper surface[J]. MATERIALS AND CORROSION-WERKSTOFFE UND KORROSION,2018,69(8):978-984. |
| APA | Dou, Wenwen,Wang, Peng,Wu, Jiajia,Gu, Tingyue,&Zhang, Dun.(2018).Strong acid resistance from electrochemical deposition of WO3 on super-hydrophobic CuO-coated copper surface.MATERIALS AND CORROSION-WERKSTOFFE UND KORROSION,69(8),978-984. |
| MLA | Dou, Wenwen,et al."Strong acid resistance from electrochemical deposition of WO3 on super-hydrophobic CuO-coated copper surface".MATERIALS AND CORROSION-WERKSTOFFE UND KORROSION 69.8(2018):978-984. |
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| Strong acid resistan（1000KB） | 期刊论文 | 出版稿 | 开放获取 | CC BY-NC-SA | View | |
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