Improvement of active corrosion protection of carbon steel by water-based epoxy coating with smart CeO2 nanocontainers
Liu, Xuehui1; Gu, Chuanjun2; Wen, Zhehua1; Hou, Baorong1,3
2018-02-01
发表期刊PROGRESS IN ORGANIC COATINGS
ISSN0300-9440
卷号115页码:195-204
通讯作者Hou, Baorong(brhou@qdio.ac.cn)
摘要Water-based epoxy coating containing CeO2 nanocontainers was successfully applied on carbon steel for corrosion protection. CeO2 nanocontainers were loaded with the corrosion inhibitor benzotriazole (BTA). Polyelectrolyte multilayers were deposited on the loaded nanocontainers by layer-by-layer assembly method. Responsive release of BTA molecules were studied in water media at different pH values using UV vis spectroscopy. The anticorrosive performance of the epoxy coatings doped with 0.5 wt% of smart nanocontainers was tested by immersion of the coated carbon steel in 0.5 M NaCl solution. Electrochemical impedance spectroscopy (EIS) was used to estimate the influence of smart nanocontainers on the passive corrosion resistance. The self healing performance of the coating with modified CeO2 nanocontainers was studied by scanning Kelvin probe (SIT). From results of EIS and SKP, the addition of pH-sensitive nanocontainers into the epoxy resin inhibited the corrosion activities on the metal surface, showing a promising strategy for developing water-based epoxy coatings with long term protection performance.
关键词CeO2 Smart nanocontainers Corrosion protection Self-healing coating EIS
DOI10.1016/j.porgcoat.2017.10.015
收录类别SCI
语种英语
资助项目National Basic Research Program of China[2014CB643304] ; National Basic Research Program of China[2014CB643304]
WOS研究方向Chemistry ; Materials Science
WOS类目Chemistry, Applied ; Materials Science, Coatings & Films
WOS记录号WOS:000425558700026
出版者ELSEVIER SCIENCE SA
引用统计
被引频次:79[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.qdio.ac.cn/handle/337002/158051
专题海洋环境腐蚀与生物污损重点实验室
通讯作者Hou, Baorong
作者单位1.Shandong Univ, Inst Marine Sci & Technol, 27 South Shanda Rd, Jinan 250100, Shandong, Peoples R China
2.Guangxi Univ, Sch Chem & Chem Engn, 100 Daxue East Rd, Nanning 530004, Peoples R China
3.Chinese Acad Sci, Natl Engn Ctr Marine Corros Protect, Inst Oceanol, 7 Nanhai Rd, Qingdao 266071, Peoples R China
通讯作者单位中国科学院海洋研究所
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Liu, Xuehui,Gu, Chuanjun,Wen, Zhehua,et al. Improvement of active corrosion protection of carbon steel by water-based epoxy coating with smart CeO2 nanocontainers[J]. PROGRESS IN ORGANIC COATINGS,2018,115:195-204.
APA Liu, Xuehui,Gu, Chuanjun,Wen, Zhehua,&Hou, Baorong.(2018).Improvement of active corrosion protection of carbon steel by water-based epoxy coating with smart CeO2 nanocontainers.PROGRESS IN ORGANIC COATINGS,115,195-204.
MLA Liu, Xuehui,et al."Improvement of active corrosion protection of carbon steel by water-based epoxy coating with smart CeO2 nanocontainers".PROGRESS IN ORGANIC COATINGS 115(2018):195-204.
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