IOCAS-IR  > 海洋环境腐蚀与与生物污损重点实验室
Ultrasound-assisted synthesis of wear-resistant Zn-Ferrocene composite coatings with high anticorrosive properties in alkaline environments
Zhai, Xiaofan1,2,5; Li, Ke1,2,3; Guan, Fang1,2,5; Wang, Nan1,2,3; Agievich, Maria4; Duan, Jizhou1,2,5; Hou, Baorong1,2,5
2018-12-25
Source PublicationSURFACE & COATINGS TECHNOLOGY
ISSN0257-8972
Volume356Pages:19-28
Corresponding AuthorZhai, Xiaofan(zhaixf@qdio.ac.cn) ; Duan, Jizhou(duanjz@qdio.ac.cn)
AbstractZn coatings are widely applied due to their low cost and negative potential in steel construction and reinforcing steel bars in concretes. However, Zn coatings have been found to perform unsatisfactorily in moist and alkaline environments. In the aqueous alkali environments that inevitably form when concretes fail, galvanized reinforcing steel bars have extremely low corrosion resistance and, consequently, are subject to corrosion. Facing these problems, various additives, including organic and inorganic compounds, have been introduced into Zn coatings to obtain enhanced corrosion resistance, with fewer experiments focusing on organometallic compound composited coatings. As a typical organometallic compound, ferrocene possesses high resistance to corrosive media, such as acids and alkalis. This makes ferrocene an extremely appropriate additive for composite Zn coatings. In this study, Zn-Ferrocene composite coatings were synthesized via electrodeposition with ultrasound assistance. Ferrocene was successfully incorporated using electrochemical control, with a maximum ferrocene content determined to be 19.4% of the C present in the composite coating. The surface morphologies and crystalline structures of the resultant coatings were significantly altered to thin, flake-like hexagonal crystals, a characteristic that was associated with the electrodepositing atomic matrix. The addition of ferrocene greatly improved the wear resistance of the composite coatings, with a 25% mass loss of pure zinc within the coating. The best properties were obtained at an ultrasound assistance level of 15 W. In addition, the corrosion mechanism of the composite coatings was studied at the molecular level. It was found that the corrosion resistance of the composite coatings in alkaline solutions was noticeably enhanced, with an R at value doubled showing the charge transfer process was inhibited. These results indicate that ultrasound-assisted Zn-Ferrocene composite coatings hold much promise for their potential use in reinforced steel bars in concretes and other abrasive environments.
KeywordZn-Ferrocene Composite coating Ultrasound-assisted electrodepositing Wear resistance Corrosion behavior
DOI10.1016/j.surfcoat.2018.09.047
Indexed BySCI
Language英语
Funding ProjectNational Natural Science Foundation of China[41811530090] ; National Natural Science Foundation of China[41706080] ; Key Research and Development Program of Shandong Province[2018GHY115029]
WOS Research AreaMaterials Science ; Physics
WOS SubjectMaterials Science, Coatings & Films ; Physics, Applied
WOS IDWOS:000449131100003
PublisherELSEVIER SCIENCE SA
Citation statistics
Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.qdio.ac.cn/handle/337002/156577
Collection海洋环境腐蚀与与生物污损重点实验室
Corresponding AuthorZhai, Xiaofan; Duan, Jizhou
Affiliation1.Chinese Acad Sci, Inst Oceanol, CAS Key Lab Marine Environm Corros & Biofouling, 7 Nanhai Rd, Qingdao 266071, Peoples R China
2.Pilot Natl Lab Marine Sci & Technol Qingdao, Open Studio Marine Corros & Protect, 1 Wenhai Rd, Qingdao 266235, Peoples R China
3.Univ Chinese Acad Sci, 19 Jia Yuquan Rd, Beijing 100049, Peoples R China
4.Immanuil Kant Baltic Fed Univ, Inst Living Syst, A Nevskogo 14, Kaliningrad 236041, Russia
5.Chinese Acad Sci, Ctr Ocean Mega Sci, 7 Nanhai Rd, Qingdao 266071, Peoples R China
First Author AffilicationInstitute of Oceanology, Chinese Academy of Sciences
Corresponding Author AffilicationInstitute of Oceanology, Chinese Academy of Sciences
Recommended Citation
GB/T 7714
Zhai, Xiaofan,Li, Ke,Guan, Fang,et al. Ultrasound-assisted synthesis of wear-resistant Zn-Ferrocene composite coatings with high anticorrosive properties in alkaline environments[J]. SURFACE & COATINGS TECHNOLOGY,2018,356:19-28.
APA Zhai, Xiaofan.,Li, Ke.,Guan, Fang.,Wang, Nan.,Agievich, Maria.,...&Hou, Baorong.(2018).Ultrasound-assisted synthesis of wear-resistant Zn-Ferrocene composite coatings with high anticorrosive properties in alkaline environments.SURFACE & COATINGS TECHNOLOGY,356,19-28.
MLA Zhai, Xiaofan,et al."Ultrasound-assisted synthesis of wear-resistant Zn-Ferrocene composite coatings with high anticorrosive properties in alkaline environments".SURFACE & COATINGS TECHNOLOGY 356(2018):19-28.
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