Antifouling Properties and Release of Dissolved Copper of Cold Spray Cu/Cu2O Coatings for Ships and Steel Structures in Marine Environment
Ding, Rui1,2; Li, Xiangbo3; Wang, Jia4; Li, Weihua5; Wang, Xiao6; Gui, Taijiang6
2018-11-01
发表期刊JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE
ISSN1059-9495
卷号27期号:11页码:5947-5963
通讯作者Ding, Rui(dmoyuyang@foxmail.com)
摘要At the submarine screen doors of ships, the flow of water was fast and organic coatings were easy to peel off. To solve the problems of biofouling, the Cu/Cu2O coatings were prepared by cold spray technology. In this paper, the release mechanism of effective antifouling components of the coatings was studied by micro-domain electrochemical potential scanning technique. Cuprous oxide in the coatings and the surrounding copper constituted micro-cells which accelerated the local electrochemical dissolution of copper. Cuprous oxide acted as the cathode, and the surrounding copper acted as the anode. Meanwhile, under the action of current, chloride ions were transferred from cathode to the anode and promoted local electrochemical dissolution of copper. Experiments show that the higher the Cu2O content in the coatings, the greater the release rate of dissolved copper and inhibitory effect on diatoms. In the environments varied in dissolved oxygen, salinity, temperature and flow rate, the coatings maintained sufficient release rate of dissolved copper, unless the salinity was very low. Most of the dissolved copper was provided by the electrochemical dissolution process of copper. Whether in the indoor test or marine environment experiments, 30% Cu2O coatings show the best performance. After insulating layer was sprayed, the effect of antifouling was improved evidently and the coatings were applied to the submarine screen doors of ships.
关键词antifouling cold spray copper corrosion galvanic cuprous oxide
DOI10.1007/s11665-018-3580-7
收录类别SCI
语种英语
资助项目China Postdoctoral Science Fund[2018M632726] ; Qingdao Independent Innovation Special Project[16-7-1-2-ZDZXX] ; National Science Fund[51525903] ; Qingdao National Laboratory for Marine Science and Technology[2017ASTCP-OS09] ; China Postdoctoral Science Fund[2018M632726] ; Qingdao Independent Innovation Special Project[16-7-1-2-ZDZXX] ; National Science Fund[51525903] ; Qingdao National Laboratory for Marine Science and Technology[2017ASTCP-OS09]
WOS研究方向Materials Science
WOS类目Materials Science, Multidisciplinary
WOS记录号WOS:000450259200036
出版者SPRINGER
引用统计
被引频次:7[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.qdio.ac.cn/handle/337002/156106
专题海洋环境腐蚀与生物污损重点实验室
通讯作者Ding, Rui
作者单位1.Yantai Univ, Coll Oceanog, Yantai 264005, Peoples R China
2.Chinese Acad Sci, Inst Oceanol, Qingdao 266071, Peoples R China
3.Luoyang Ship Mat Res Inst LSRMI, Sci & Technol Marine Corros & Protect Lab, Qingdao 266101, Peoples R China
4.Ocean Univ China, Qingdao 266001, Peoples R China
5.Sun Yat Sen Univ, Coll Chem Engn & Technol, Zhuhai 519082, Peoples R China
6.Marine Chem Res Inst, State Key Lab Marine Coatings, Qingdao 266071, Peoples R China
第一作者单位中国科学院海洋研究所
通讯作者单位中国科学院海洋研究所
推荐引用方式
GB/T 7714
Ding, Rui,Li, Xiangbo,Wang, Jia,et al. Antifouling Properties and Release of Dissolved Copper of Cold Spray Cu/Cu2O Coatings for Ships and Steel Structures in Marine Environment[J]. JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE,2018,27(11):5947-5963.
APA Ding, Rui,Li, Xiangbo,Wang, Jia,Li, Weihua,Wang, Xiao,&Gui, Taijiang.(2018).Antifouling Properties and Release of Dissolved Copper of Cold Spray Cu/Cu2O Coatings for Ships and Steel Structures in Marine Environment.JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE,27(11),5947-5963.
MLA Ding, Rui,et al."Antifouling Properties and Release of Dissolved Copper of Cold Spray Cu/Cu2O Coatings for Ships and Steel Structures in Marine Environment".JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE 27.11(2018):5947-5963.
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