| Iron-catalyzed alkynylation of tertiary aliphatic amines with 1-iodoalkynes to synthesize propargylamines |
| Ma, Lina1,2,3; Shi, Xiaolin1,2,3; Li, Xiaowei1,2,3; Shi, Dayong1,2,3
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| 2018-12-21
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发表期刊 | ORGANIC CHEMISTRY FRONTIERS
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ISSN | 2052-4129
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卷号 | 5期号:24页码:3515-3519 |
通讯作者 | Shi, Dayong(shidayong@qdio.ac.cn)
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摘要 | A method of alkynylation of tertiary aliphatic amines with 1-iodoalkynes has been developed in the presence of FeCl2 as a catalyst and tert-butyl hydroperoxide as an oxidant. With this method, a variety of propargylamines were obtained in good to excellent yields from inexpensive and readily available reagents. The studies on the possible reaction pathway suggest that this reaction proceeds through a radical process. |
DOI | 10.1039/c8qo01028e
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收录类别 | SCI
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语种 | 英语
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资助项目 | CPSF-CAS Joint Foundation for Excellent Postdoctoral Fellows[2017LH024]
; National Natural Science Foundation of China[81773586]
; National Natural Science Foundation of China[81703354]
; Key research and development project of Shandong province[2016GSF201193]
; Key research and development project of Shandong province[2016ZDJS07A13]
; Key research and development project of Shandong province[2016GSF115002]
; Key research and development project of Shandong province[2016GSF115009]
; Key Research Program of Frontier Sciences, CAS[QYZDB-SSW-DQC014]
; Shandong Provincial Natural Science Foundation for Distinguished Young Scholars[JQ201722]
; National Program for Support of Top-notch Young Professionals
; Taishan scholar Youth Project of Shandong province
; Project of Discovery, Evaluation and Transformation of Active Natural Compounds, Strategic Biological Resources Service Network Program of the Chinese Academy of Sciences[ZSTH-026]
; CPSF-CAS Joint Foundation for Excellent Postdoctoral Fellows[2017LH024]
; National Natural Science Foundation of China[81773586]
; National Natural Science Foundation of China[81703354]
; Key Research and Development Project of Shandong Province[2016GSF201193]
; Key Research and Development Project of Shandong Province[2016ZDJS07A13]
; Key Research and Development Project of Shandong Province[2016GSF115002]
; Key Research and Development Project of Shandong Province[2016GSF115009]
; Key Research Program of Frontier Sciences, CAS[QYZDB-SSW-DQC014]
; Shandong Provincial Natural Science Foundation for Distinguished Young Scholars[JQ201722]
; National Program for Support of Top-notch Young Professionals
; Taishan Scholar Youth Project of Shandong Province
; Project of Discovery, Evaluation and Transformation of Active Natural Compounds, Strategic Biological Resources Service Network Program of the Chinese Academy of Sciences[ZSTH-026]
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WOS研究方向 | Chemistry
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WOS类目 | Chemistry, Organic
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WOS记录号 | WOS:000452114300003
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出版者 | ROYAL SOC CHEMISTRY
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引用统计 |
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文献类型 | 期刊论文
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条目标识符 | http://ir.qdio.ac.cn/handle/337002/155796
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专题 | 实验海洋生物学重点实验室
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通讯作者 | Shi, Dayong |
作者单位 | 1.Chinese Acad Sci, Inst Oceanol, Key Lab Expt Marine Biol, Qingdao 266071, Peoples R China 2.Qingdao Natl Lab Marine Sci & Technol, Lab Marine Drugs & Bioprod, Qingdao 266237, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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第一作者单位 | 实验海洋生物学重点实验室
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通讯作者单位 | 实验海洋生物学重点实验室
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推荐引用方式 GB/T 7714 |
Ma, Lina,Shi, Xiaolin,Li, Xiaowei,et al. Iron-catalyzed alkynylation of tertiary aliphatic amines with 1-iodoalkynes to synthesize propargylamines[J]. ORGANIC CHEMISTRY FRONTIERS,2018,5(24):3515-3519.
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APA |
Ma, Lina,Shi, Xiaolin,Li, Xiaowei,&Shi, Dayong.(2018).Iron-catalyzed alkynylation of tertiary aliphatic amines with 1-iodoalkynes to synthesize propargylamines.ORGANIC CHEMISTRY FRONTIERS,5(24),3515-3519.
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MLA |
Ma, Lina,et al."Iron-catalyzed alkynylation of tertiary aliphatic amines with 1-iodoalkynes to synthesize propargylamines".ORGANIC CHEMISTRY FRONTIERS 5.24(2018):3515-3519.
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