Synthesis of EDTA-assisted CeVO4 nanorods as robust peroxidase mimics towards colorimetric detection of H2O2

doi:10.1039/c6tb01881e

	Synthesis of EDTA-assisted CeVO4 nanorods as robust peroxidase mimics towards colorimetric detection of H2O2
	Ju, Peng1,2 ; Yu, Yanzhen 3; Wang, Min 1,4; Zhao, Yun 1; Zhang, Dun 5; Sun, Chengjun 3,6; Han, Xiuxun 1,2
	2016
发表期刊	JOURNAL OF MATERIALS CHEMISTRY B
卷号	4 期号:38 页码:6316-6325
文章类型	Article
摘要	In this paper, CeVO4 materials were developed as highly efficient biomimetic catalysts for the first time to detect H2O2. These CeVO4 materials were prepared by a facile hydrothermal method with the assistance of EDTA, exhibiting different morphologies, surface properties, and distinct peroxidase mimetic activities. Among them, CeVO4-2 nanorods (NRs) were proved to display the best intrinsic peroxidase-like property compared to other CeVO4 samples due to their more negative potential and larger BET specific surface area, which could efficiently catalyze the oxidation of 3,3',5,5'-tetramethylbenzidine (TMB) in the presence of H2O2 to generate a blue oxide. Based on the excellent peroxidase mimetic catalytic activity of CeVO4-2 NRs, a simple, convenient and visual H2O2 detection system was successfully established. The detection limit of H2O2 could reach as low as 0.07 mu M. Moreover, the CeVO4-2 NR-based assay system presented an excellent selectivity, practicability, long-term stability, and reusability. The peroxidase-like catalytic mechanism of CeVO4-2 NRs was proposed on the basis of active species trapping experiments. This work provides a novel, convenient, rapid, and ultrasensitive system for the colorimetric detection of H2O2, which has a bright prospect in H2O2 detection and biomedical analysis.
DOI	10.1039/c6tb01881e
收录类别	SCI
语种	英语
WOS记录号	WOS:000385378900004
引用统计	被引频次：44[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
版本	出版稿
条目标识符	http://ir.qdio.ac.cn/handle/337002/136164
专题	海洋环境腐蚀与生物污损重点实验室
作者单位	1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Lab Clean Energy Chem & Mat, 18 Tianshui Middle Rd, Lanzhou 730000, Peoples R China 2.Qingdao Ctr Resource Chem & New Mat, 36 Jinshui Rd, Qingdao 266100, Peoples R China 3.State Ocean Adm, Inst Oceanog 1, Marine Ecol Ctr, 6 Xianxialing Rd, Qingdao 266061, Peoples R China 4.Univ Chinese Acad Sci, 19 Jia Yuquan Rd, Beijing 100039, Peoples R China 5.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, 7 Nanhai Rd, Qingdao 266071, Peoples R China 6.Qingdao Natl Lab Marine Sci & Technol, Lab Marine Drugs & Bioprod, Qingdao 266071, Peoples R China
推荐引用方式 GB/T 7714	Ju, Peng,Yu, Yanzhen,Wang, Min,et al. Synthesis of EDTA-assisted CeVO4 nanorods as robust peroxidase mimics towards colorimetric detection of H2O2[J]. JOURNAL OF MATERIALS CHEMISTRY B,2016,4(38):6316-6325.
APA	Ju, Peng.,Yu, Yanzhen.,Wang, Min.,Zhao, Yun.,Zhang, Dun.,...&Han, Xiuxun.(2016).Synthesis of EDTA-assisted CeVO4 nanorods as robust peroxidase mimics towards colorimetric detection of H2O2.JOURNAL OF MATERIALS CHEMISTRY B,4(38),6316-6325.
MLA	Ju, Peng,et al."Synthesis of EDTA-assisted CeVO4 nanorods as robust peroxidase mimics towards colorimetric detection of H2O2".JOURNAL OF MATERIALS CHEMISTRY B 4.38(2016):6316-6325.

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