Synthesis, characterization, and controlled release antibacterial behavior of antibiotic intercalated Mg-Al layered double hydroxides
Wang, Yi; Zhang, Dun; Zhang, D (reprint author), Chinese Acad Sci, Shandong Prov Key Lab Corros Sci, Inst Oceanol, Qingdao 266071, Peoples R China.
2012-11-01
发表期刊MATERIALS RESEARCH BULLETIN
ISSN0025-5408
卷号47期号:11页码:3185-3194
文章类型Article
摘要Antibiotic-inorganic clay composites including four antibiotic anions, namely, benzoate (BZ), succinate (SO), benzylpenicillin (BP), and ticarcillin (TC) anions, intercalated Mg-Al layered double hydroxides (LDHs) were synthesized via ion-exchange. Powder X-ray diffraction and Fourier transform infrared spectrum analyses showed the successful intercalation of antibiotic anion into the LDH interlayer. BZ and BP anions were accommodated in the interlayer region as a bilayer, whereas SU and TC anions were intercalated in a monolayer arrangement. Kinetic simulation of the release data indicated that ion-exchange was responsible for the release process, and the diffusion through the particles was the rate-limiting step. The antibacterial capabilities of LDHs loaded with antibiotic anion toward Micrococcus lysodeikticus growth were analyzed using a turbidimetric method. Significant high inhibition rate was observed when LDH nanohybrid was introduced in 3.5% NaCl solution. Therefore, this hybrid material may be applied as nanocontainer in active antifouling coating for marine equipment. (C) 2012 Elsevier Ltd. All rights reserved.
关键词Layered Compounds Intercalation Reactions X-ray Diffraction Diffusion Microstructure
学科领域Materials Science, Multidisciplinary
DOI10.1016/j.materresbull.2012.08.029
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收录类别SCI
语种英语
WOS记录号WOS:000311865200019
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被引频次:38[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.qdio.ac.cn/handle/337002/12485
专题海洋环境腐蚀与生物污损重点实验室
通讯作者Zhang, D (reprint author), Chinese Acad Sci, Shandong Prov Key Lab Corros Sci, Inst Oceanol, Qingdao 266071, Peoples R China.
作者单位Chinese Acad Sci, Shandong Prov Key Lab Corros Sci, Inst Oceanol, Qingdao 266071, Peoples R China
第一作者单位中国科学院海洋研究所
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Wang, Yi,Zhang, Dun,Zhang, D . Synthesis, characterization, and controlled release antibacterial behavior of antibiotic intercalated Mg-Al layered double hydroxides[J]. MATERIALS RESEARCH BULLETIN,2012,47(11):3185-3194.
APA Wang, Yi,Zhang, Dun,&Zhang, D .(2012).Synthesis, characterization, and controlled release antibacterial behavior of antibiotic intercalated Mg-Al layered double hydroxides.MATERIALS RESEARCH BULLETIN,47(11),3185-3194.
MLA Wang, Yi,et al."Synthesis, characterization, and controlled release antibacterial behavior of antibiotic intercalated Mg-Al layered double hydroxides".MATERIALS RESEARCH BULLETIN 47.11(2012):3185-3194.
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