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Inhibition Behavior of Chito-Oligosaccharide Schiff Base Derivatives for Mild Steel in 3.5% NaCl Solution | |
Ma, Fubin1,2; Li, Weihua1; Tian, Huiwen1; Kong, Qinglin3; Hou, Baorong1; Ma, FB (reprint author), Chinese Acad Sci, Inst Oceanol, Qingdao 266071, Peoples R China. | |
2012-11-01 | |
发表期刊 | INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE |
ISSN | 1452-3981 |
卷号 | 7期号:11页码:10909-10922 |
文章类型 | Article |
摘要 | Two new corrosion inhibitors of chito-oligosaccharide schiff base (CSB) and carboxymethyl chito-oligosaccharide schiff base (CM-CSB) were investigated by means of weight loss, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) measurements in 3.5% NaCl solution at different concentrations. The surface corrosion morphology of specimens was examined by scanning electron microscopy (SEM) and the inhibition mechanism was analyzed by adsorption isotherm fitting and quantum chemical calculation. The results showed that for CSB the inhibition efficiency increased at first, then decreased and reached the maximum at 200mg/L and acted as a mixed type inhibitor; the CM-CSB had excellent inhibition performance and behaved as a cathode-based mixed corrosion inhibitor. The adsorption of CM-CSB obeys the Langmuir isotherm. |
关键词 | Chito-oligosaccharide Schiff Base Electrochemical Measurements Langmuir Adsorption Quantum Chemical Calculation |
学科领域 | Electrochemistry |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000312934600045 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.qdio.ac.cn/handle/337002/12470 |
专题 | 海洋环境腐蚀与生物污损重点实验室 |
通讯作者 | Ma, FB (reprint author), Chinese Acad Sci, Inst Oceanol, Qingdao 266071, Peoples R China. |
作者单位 | 1.Chinese Acad Sci, Inst Oceanol, Qingdao 266071, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Univ Melbourne, Melbourne, Vic 3010, Australia |
第一作者单位 | 中国科学院海洋研究所 |
推荐引用方式 GB/T 7714 | Ma, Fubin,Li, Weihua,Tian, Huiwen,et al. Inhibition Behavior of Chito-Oligosaccharide Schiff Base Derivatives for Mild Steel in 3.5% NaCl Solution[J]. INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE,2012,7(11):10909-10922. |
APA | Ma, Fubin,Li, Weihua,Tian, Huiwen,Kong, Qinglin,Hou, Baorong,&Ma, FB .(2012).Inhibition Behavior of Chito-Oligosaccharide Schiff Base Derivatives for Mild Steel in 3.5% NaCl Solution.INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE,7(11),10909-10922. |
MLA | Ma, Fubin,et al."Inhibition Behavior of Chito-Oligosaccharide Schiff Base Derivatives for Mild Steel in 3.5% NaCl Solution".INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE 7.11(2012):10909-10922. |
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