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Dendritic core-shell structure preparation by a facile consecutive electrochemical crystal growth method | |
Qiu, Ri1,2; Zhang, Dun1; Wang, Peng1; Zhang, D (reprint author), Chinese Acad Sci, Inst Oceanol, Key Lab Corros Sci, 7 Nanhai Rd, Qingdao 266071, Shandong, Peoples R China. | |
2012-10-30 | |
发表期刊 | ELECTROCHIMICA ACTA |
ISSN | 0013-4686 |
卷号 | 81页码:112-116 |
文章类型 | Article |
摘要 | In this study, dendritic Co@Cu is prepared to illustrate a facile strategy to acquire bimetallic dendritic core-shell structure. The core and shell metals are both obtained by electrochemical crystal growth process. The leading parameter, overpotential, endows inner core dendritic shape by surpassing the critical value. Meanwhile, it also determines Cu shell morphology from flat surface to dendritic structure by adopting different value. The Cu dendrite on Co dendritic core constructs a super-dendrite, which is regarded as a higher class of hierarchical structure. Sophisticated techniques such as field-emission scanning electron microscopy, energy dispersive spectroscopy and X-ray powder diffraction are devoted to reveal the external morphology of the as-obtained material and verify the core-shell characteristic. (c) 2012 Elsevier Ltd. All rights reserved. |
关键词 | Dendritic Morphology Cu@co Consecutive Electrochemical Crystal Growth Bimetallic Core-shell Structure |
学科领域 | Electrochemistry |
DOI | 10.1016/j.electacta.2012.07.079 |
URL | 查看原文 |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000309330500017 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.qdio.ac.cn/handle/337002/12463 |
专题 | 海洋环境腐蚀与生物污损重点实验室 |
通讯作者 | Zhang, D (reprint author), Chinese Acad Sci, Inst Oceanol, Key Lab Corros Sci, 7 Nanhai Rd, Qingdao 266071, Shandong, Peoples R China. |
作者单位 | 1.Chinese Acad Sci, Inst Oceanol, Key Lab Corros Sci, Qingdao 266071, Shandong, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
第一作者单位 | 中国科学院海洋研究所 |
推荐引用方式 GB/T 7714 | Qiu, Ri,Zhang, Dun,Wang, Peng,et al. Dendritic core-shell structure preparation by a facile consecutive electrochemical crystal growth method[J]. ELECTROCHIMICA ACTA,2012,81:112-116. |
APA | Qiu, Ri,Zhang, Dun,Wang, Peng,&Zhang, D .(2012).Dendritic core-shell structure preparation by a facile consecutive electrochemical crystal growth method.ELECTROCHIMICA ACTA,81,112-116. |
MLA | Qiu, Ri,et al."Dendritic core-shell structure preparation by a facile consecutive electrochemical crystal growth method".ELECTROCHIMICA ACTA 81(2012):112-116. |
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